Electrochemical Cells Flashcards

1
Q

Anode

A

Electrode of a voltaic or electrolytic cell where oxidation (loss of electrons) occurs.

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2
Q

Cathode

A

Electrode of a voltaic or electrolytic cell where reduction (gain of electrons) occurs.

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3
Q

Cathodic Protection

A

Effective method of preventing corrosion of iron in which the iron is forced to become the cathode by using either impressed current or a sacrificial anode.

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4
Q

Corrosion

A

Electrochemical process in which a metal reacts with substances in the environment, returning the metal to an ore-like state (metal becomes an oxide- is oxidized).

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5
Q

Electrical Current (I)

A

A measure of the rate of fow or charge past of point in an electrical circuit; measured by an ammeter in amperes (A).

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6
Q

Electric Potential Difference (V)

A

The energy difference, per unit charge, between any two points in an electrical circuit; measured in volts (V); also called voltage.

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7
Q

Electrode

A

A solid electrical conductor.

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8
Q

Electrolysis

A

The process of supplying electrical energy to force a non-spontaneous redox reaction to occur.

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9
Q

Electrolyte

A

A substance that conducts electricity in aqueous solution; also a liquid such as a molten solid that conducts electricity.

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10
Q

Electrolytic Cell

A

A cell in which a non-spontaneous redox reaction is forced to occur; a combination of two electrodes, an electrolyte, and an external power source.

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11
Q

Faraday Constant (F)

A

The quantity of charge transferred for every mole of electrons that flows in the cell; 9.65 x 10^4 C/mol

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12
Q

Faraday’s Law

A

The statement: the mass of an element produced or consumed at an electrode is directly proportional to the time the cell operates, as long as the current is constant or vice versa.

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13
Q

Fuel Cell

A

An electric cell that produces electricity by the reaction of a fuel that is continuously supplied to keep the cell operating.

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14
Q

Half-cell

A

An electrode-electrolyte combination forming one-half of a complete cell.

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15
Q

Inert Electrode

A

An unreactive solid conductor in a cell that provides a location to connect a wire and a surface on which a half-reaction can occur.

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16
Q

Porous Boundary

A

A physical barrier separating two electrolytes while still permitting ions to move between the two solutions through tiny openings.

17
Q

Primary Cell

A

A cell that cannot be recharged, usually due to irreversible side reactions.

18
Q

Reference Half-Cell

A

A half-cell that is chosen as a reference and is arbitrarily assigned an electrode potential of exactly zero volts; a standard hydrogen electrode.

19
Q

Secondary Cell

A

A rechargeable cell.

20
Q

Standard Cell

A

A voltaic cell in which each half-cell contains all entities in the half-reaction equation at SATP conditions, with a concentration of 1.0 mol/L for the aqueous solutions

21
Q

Standard Cell Potential

A

The maximum electrical potential difference (voltage) of the cell operating under standard conditions; the energy difference (per unit of charge) between the cathode and the anode.

22
Q

Standard Reduction Potential

A

The ability of a standard half-cell to attract/gain electrons under standard conditions.

23
Q

Voltaic Cell

A

An arrangement of two half-cells, separated by a porous boundary, that spontaneously produces energy.