Electrochemical Flashcards

1
Q

Are the strongest reducing agents positive or negative

A

Negative

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2
Q

In a Galvanic cell, what charge does the anode have?

A

Negative

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3
Q

A cell’s standard potential is the potential of the cell under standard state conditions”

A

is in the data booklet

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4
Q

In an electrolytic cell what charge does the anode have?

A

The anode has a positive charge.

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4
Q

Define the standard electrode potential of a half-cell (Eθ)?

A

The standard electrode potential of a half-cell is the voltage of a half-cell compared with a standard hydrogen electrode.

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4
Q

In an electrolytic cell what charge does the anode have?

A

positive

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5
Q

Name the two types of electrochemical cells.

A

Galvanic and electrolytic

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5
Q

Eo values are measured under specific conditions. What are they?

A

1M concentration of electrolyte, 298K and 1 atmosphere

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5
Q

Standard electrode potentials are generally written as?

A

Reduction half equation

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5
Q

How is the potential cell difference of a galvanic cell calculated?

A

By subtracting the cell potential of the anode from the cathode, the cell potential of the galvanic cell as a whole can be calculated. E0 = E0 reduction - E0 oxidation

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6
Q

What are electrolytes?

A

An ionic substance which is either molten or an aqueous solution

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6
Q

What are Eo values?

A

The symbol represents the Cell Potential. It shows the voltage produced in a Galvanic half-cell.

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6
Q

What charge does the cathode have in an electrolytic cell?

A

The cathode has a negative charge in electrolytic cells

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6
Q

What does Eθ have to equal to be considered a spontaneous reaction?

A

Positive Value

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7
Q

What are galvanic cells used for?

A

Source of electrical energy, batteries

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7
Q

What equation calculates the overall cell potential?

A

The cell potential is the difference between the reduction potentials: Eocell=Eored−Eooxid

7
Q

What are standard conditions under which standard electrode potentials are measured?

A

250C, 1 atm and 1M

8
Q

What industrial situations use electrolytic cells?

A

Some examples of industrial situations in which electrolytic cells would be of use include metal plating and copper purifications.

8
Q

What are the units for standard electrode potentials?

9
Q

What is an electrode?

A

A solid conductor of electricity

9
Q

What is a galvanic cell?

A

A cell in which spontaneous oxidation- reduction reactions produce electrical energy

9
Q

What is the difference between cell potential and standard cell potential?

A

“The cell potential is the measure of the potential difference between two half cells in an electrochemical cell.

10
Q

What is an electrolyte?

A

A solution that contains positive ions (cations) and negative ions (anions)

10
Q

What is the gain of electrons called?

10
What is an external circuit in a Galvanic cell?
Wires that connect the anode to the cathode and allow the movement of electrons to occur
10
What is the job of the salt bridge in a Galvanic cell?
It is a connection between the 2 half cells that allows the movement of charged ions
11
What is electrolysis?
The process by which electrical energy is passed into a cell to cause a non- spontaneous reaction to occur
12
What is the standard electrode potential of a half-cell a measure of?
This potential is a measure of the energy per unit charge which is available from the oxidation/reduction reactions to drive the reaction
13
What is oxidation?
Oxidation is the loss of electrons
14
What occurs at the anode?
Oxidation (Loss of electrons) occurs at the anode
15
What occurs at the cathode?
Reduction (gain of electrons) occurs at the cathode
16
What type of electrode is needed for a molten electrolytic cell?
The electrode must be an inert material; have a higher melting point then the molten solution
17
What type of a reaction occurs in a Galvanic cell?
A spontaneous REDOX reaction
18
What type of reaction occurs in electrolytic cells?
A forced non- spontaneous reaction.
19
What type of chemical reaction occurs in a galvanic cell, Spontaneous, or non- spontaneous?
Spontaneous
20
Why does a Galvanic cell need to be separated into two half cells?
In order to utilise the current produced and start or stop the spontaneous reaction
21
What type of electrochemical cell contains a salt bridge?
Galvanic cell
22
Why is molten electrolysis rarely seen/used?
It requires a large amount of energy to both run the cell as well as to keep the solution molten.
23
What type of electrochemical cell uses energy from an external source?
Electrolytic cell