DM - Transition metals Flashcards

1
Q

Where are transition metals found in the periodic table?

A

In the d-block (in the middle of the periodic table).

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Most of the elements in the d-block are what?

A

Transition metals.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Which d-block elements do we mainly need to know?

A

Those in the first row from titanium to copper.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is a transition metal?

A

A d-block element that can form at least one stable ion with an incomplete d sub-shell.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

How many electrons can a d sub-shell hold?

A

10

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What must a transition metal form?

A

At least one ion that has between 1 and 9 electrons in the d sub-shell.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Which elements in period 4 in the d-block are transition metals?

A

All except scandium and zinc.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Which of the transition metals electron configurations are different?

A

chromium and copper.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

How is the electron configuration of chromium different?

A

It prefers to have one electrons in each orbital of the 3d subshell and one in the 4s subshell to give it more stability.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

How is the electron configuration of copper different?

A

Prefers to have a full 3d subshell and just one electron in the 4s subshell to be more stable.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What stable ion does copper form?

A

Cu2+ ion by losing 2 electrons. The Cu2+ ion has an incomplete d subshell.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Why isn’t scandium a transition metal?

A

Because is only forms one ion, SC3+, which has an empty d subshell.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Why isn’t zinc a transition metal?

A

Only forms one ion, Zn2+, which has a full d subshell.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

When ions are formed, which electrons are removed first?

A

The s electrons.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What stable ions does iron form?

A

Fe2+

Fe3+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What special chemical properties do transition metals have?

A

1) Can exist in variable oxidation states.

2) Can form coloured ions in solution.

17
Q

What does it mean by transition metals can exist in variable oxidation states?

A

Iron can exist in the +2 oxidation state as Fe2+ ions and in the 3+ oxidation state as Fe3+ ions.

Copper can exist in the 1+ oxidation state as Cu+ ions and in the +2 oxidation state as Cu2+ ions.

18
Q

What does it mean by transition metals can form coloured ions in solution?

A

Fe2+ ions are pale green.
Fe3+ ions are yellow.
Cu2+ ions are blue.

19
Q

What colour are Fe2+ ions in solution?

A

Pale green.

20
Q

What colour are Fe3+ ions in solution?

A

Yellow.

21
Q

What colour are Cu2+ ions in solution?

A

(Pale) Blue.

22
Q

Why aren’t Cu+ ions coloured in solution?

A

Because Cu+ ions are unstable in aqueous solution and disproportionate.

2Cu+ (aq) –> Cu2+ (aq) + Cu (s)