Definitions + Rukes Flashcards

1
Q

Electron orbital

A

Region of space in which an electron spends most of its time

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2
Q

Aufbau principle

A

Electrons fill the lowest available energy level

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3
Q

Hund’s rule

A

Electrons remain impaired in every sub shell as far as possible

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4
Q

1st ionisation energy

A

Energy required to remove 1 electron from each atom in 1 mole of gaseous atoms producing 1 mole of gaseous ions

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5
Q

Linear bond angle

A

180

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6
Q

Tetrahedral bond angle

A

109.5

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7
Q

Trigonal planar bond angle

A

120

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8
Q

Pyramidal bond angle

A

107

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9
Q

Bent bond angle

A

104.5

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10
Q

Octahedral bond angle

A

90

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11
Q

Electronegativity

A

The power of an atom to attract the electrons in a covalent bond

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12
Q

Physical properties of halogens at room temperature

A

Fluorine- pale yellow gas
Chlorine- pale green gas
Bromine- dark red liquid
Iodine- shiny black crystals

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13
Q

KCl + Br2

A

Orange upper layer

Yellow lower layer

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14
Q

KCl and +I2

A

Purple upper layer

Orange lower level

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15
Q

KBr + Cl2

A

Orange upper level

Yellow lower level

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16
Q

KBr+ I2

A

Purple upper layer

Orange lower layer

17
Q

KI+ Cl2

A

Purple upper layer

Orange lower layer

18
Q

Br2+ KI

A

Purple upper layer

Orange lower layer

19
Q

Order of ion tests

A

Carbonates
Sulfates
Halides
Ammonia?

20
Q

Carbonate test

A

Dilute HNO3

Fizzing

21
Q

Sulfates test

A

Excess barium ions eg BaCl2

White precipitate

22
Q

Halide tests

A

Add acidified silver nitrate

Then check with dilute and conc ammonia

23
Q

Ammonia test

A

Add dilute NaOH

When warmed moist ph paper will turn blue

24
Q

Standard enthalpy formation

A

1 mole of substance is formed from its elements in their standard states

25
Q

Enthalpy of combustion

A

Enthalpy when 1 mole of substance is completely burned in oxygen under standard conditions

26
Q

Enthalpy of reaction

A

Enthalpy when molar quantities as stated in the chemical equation react together under standard conditions

27
Q

Enthalpy of neutralisation

A

Enthalpy when and acid and a base react together in their standard stated to form 1 mole H2O under standard conditions

28
Q

Bond enthalpy

A

The average energy required to break 1 mole of bonds in gaseous molecules

29
Q

Hess’s law

A

Enthalpy change is independent of the path taken provided initial and final conditions are the same

30
Q

Homogeneous catalyst

A

Reactants and catalyst in the same state

31
Q

Heterogeneous catalyst

A

Reactants and catalyst in different states

32
Q

Standard lattice enthalpy

A

Enthalpy change when 1 mole of an ionic compound is formed from its gaseous ions under standard conditions

33
Q

Enthalpy of atomisation

A

Enthalpy change when 1 mole of gaseous atoms is formed from the element in its standard state

34
Q

1st electron affinity

A

Enthalpy change when 1 electron is added to each atom in 1 mole of gaseous atoms to form 1 mole of gaseous 1- ions

35
Q

Enthalpy hydration

A

Enthalpy change when a solutions of ions is made from 1 mole of gaseous ions

36
Q

Enthalpy of solution

A

Enthalpy change when 1 mole of a solute dissolves to form an infinitely dilute solution

37
Q

Spontaneous reaction

A

No extra energy is need to continue the reaction