Day 002 Flashcards

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1
Q

Complete the sentence to describe the relationship between bond formation and energy: when a bond forms, ________.

A

Energy is released

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2
Q

_______: an interaction between two atoms

A

Bond

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3
Q

Complete the sentence to describe the relationship between bond formation and entropy (disorder) of the system: when a bond forms, ________.

A

Entropy of the system
increases

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4
Q

Complete the sentence: ________ bonds (type of bond) are within molecules as opposed to between molecules.

A

Covalent

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5
Q

________: the ability of atoms to attract electrons

A

Electronegativity

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6
Q

A bond in which the valence electrons are equally shared between two atoms (therefore atoms in the bond do NOT have permanent partial charges).

A

Nonpolar covalent bond

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7
Q

A bond in which the valence electrons are unequally shared between two atoms (therefore atoms in the bond have permanent partial charges):

A

Polar covalent bond

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8
Q

An interaction between atoms with full, opposite charges (ions):

A

Ionic (ion-ion) interaction

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9
Q

An interaction between a fully charged atom and an atom with an opposite partial charge:

A

Ion-dipole interaction

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10
Q

An interaction between a hydrogen with a permanent partial positive charge and a more electronegative atom (typically O or N) with a permanent partial negative charge:

A

Hydrogen bond interaction (a specific type of dipole-dipole interaction)

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11
Q

The tendency of hydrophobic molecules to group together in the presence of water:

A

Hydrophobic clustering (hydrophobic effect)

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12
Q

An extremely weak interaction between atoms that have temporary opposite charges:

A

London Dispersion Forces (LDF; type
of van der Waals interaction)

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13
Q

Nonpolar covalent bond strength (aqueous)

A

Strong

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14
Q

Polar covalent bond strength (aqueous)

A

Strong

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15
Q

Ionic (ion-ion) interaction strength (aqueous)

A

Weak

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16
Q

Ion-dipole interaction strength (aqueous)

A

Weak

17
Q

Hydrogen bond interaction strength (aqueous)

A

Weak

18
Q

Hydrophobic clustering strength (aqueous)

A

Very weak

19
Q

LDF strength (aqueous)

A

Very weak

20
Q

Hydroxyl (OH) property:

A

Polar uncharged

21
Q

Carbonyl (CO) property:

A

Polar uncharged

22
Q

Carboxyl (COOH or COO-) property:

A

Negatively charged

23
Q

Amino (NH, NH2,+NH3) property:

A

NH: Polar
+NH3: Positively charged

24
Q

Amide (C(=O)NH, CONH2) property:

A

Polar uncharged

25
Q

Sulfhydryl (SH) property:

A

Polar uncharged

26
Q

Phosphate (OPO3^2-) property:

A

Polar charged

27
Q

Methyl (CH3) property:

A

Nonpolar