CONTROLLING THE RATE Flashcards
Why is it important that chemists can control rate of reaction?
Ensure processes are both economically viable and safe
rate of reaction
change in quantity / change in time
relative rate
1 / time
collision theory
Must collide with enough kinetic energy (to overcome repulsive forces and break bonds between them) and correct geometry
minimum kinetic energy for reaction to occur
activation energy
Activated complex
An intermediate stage is reached in which a high energy, unstable arrangement of atoms is formed called activated complex
Altering factors
temperature
concentration
particle size
use of a catalyst
Temperature
increases kinetic energy and so move quicker, increasing temperature increases rate of reaction
Concentration
More reactant particles moving closer together - more collisions - so reaction rate increases
particle size
decreasing particle size, increases surface area for reaction to take place on
catalyst
provide surface for reaction to take place on
reactant molecules are held at favourable angles for geometry to be correct for reaction to occur
decreases activation energy required
tempertaure and Ea
move curve right and slighty lower
endothermic reaction
heat energy absorbed -products have more enthalpy than reactions
delta positive
activated complex in graph
highest point
catalyst in graph
lowers curve - Ea
delta H stays same