CONTROLLING THE RATE Flashcards

1
Q

Why is it important that chemists can control rate of reaction?

A

Ensure processes are both economically viable and safe

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2
Q

rate of reaction

A

change in quantity / change in time

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3
Q

relative rate

A

1 / time

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4
Q

collision theory

A

Must collide with enough kinetic energy (to overcome repulsive forces and break bonds between them) and correct geometry

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5
Q

minimum kinetic energy for reaction to occur

A

activation energy

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6
Q

Activated complex

A

An intermediate stage is reached in which a high energy, unstable arrangement of atoms is formed called activated complex

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7
Q

Altering factors

A

temperature
concentration
particle size
use of a catalyst

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8
Q

Temperature

A

increases kinetic energy and so move quicker, increasing temperature increases rate of reaction

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9
Q

Concentration

A

More reactant particles moving closer together - more collisions - so reaction rate increases

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10
Q

particle size

A

decreasing particle size, increases surface area for reaction to take place on

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11
Q

catalyst

A

provide surface for reaction to take place on

reactant molecules are held at favourable angles for geometry to be correct for reaction to occur

decreases activation energy required

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12
Q

tempertaure and Ea

A

move curve right and slighty lower

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13
Q

endothermic reaction

A

heat energy absorbed -products have more enthalpy than reactions

delta positive

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14
Q

activated complex in graph

A

highest point

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15
Q

catalyst in graph

A

lowers curve - Ea

delta H stays same

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16
Q
A