Colligative properties Flashcards
1
Q
Characteristics of osmotic pressure
A
- directly oppose osmosis (flow thru semiperm membrane)
- incr with temp (head speeds up motion of molecules in solution) > greater pressure
- not affected by chemical identiy of solute
- magnitude determined by number of particles dissolved
2
Q
Colligative properties depend on what:
A
number of solute molecules to number of solvent molecules
3
Q
Solute dissolvation and vapor pressure:
A
- solvent adheres to solute > less likely to evaporate, lowering vapor pressure
- dissolved solute near surface, physically prevent evaporation > reduce vapor pressure
4
Q
Formula for BP/FP change:
A
Change in temp = iKm
- i ion factor
- k constant for boil/freeze at certain temp
- m molality of solvent
5
Q
Equation for vapor pressure
A
vapor pressure= mol fraction (solvent) x vapor pressure (pure solvent)
6
Q
What is the relationship between vapor pressure and boiling point?
A
- adding solute reduces vapor pressure which increases Temp required to achieve boiling point
7
Q
what is boiling point definition
A
- vapor pressure equilibrium with atmospheric pressure
- thus at reduced atmospheric pressure, boiling point is lower
8
Q
what are the four colligative properties?
A
- osmostic and vapor pressure
- boiling and freezing poing