Chp. 6: Crystal Structures Flashcards
AB
Hexagonal Close-Packed (HCP) hexagonal motifs
ABC
Cubic Close-Packed (CCP) triangle motifs
atomic packing factor of HCP and CCP
.74
Slip planes for CCP
4 non-parallel slip planes, slide in 3 directions = 12 slip systems
Slip planes for HCP
no close-packed planes, only 3 slip systems, not very ductile
Body Centered Cube (BBC)
atoms on corners of cube but also one at center, rather than one at center of each face.
Interstices
BBS crystals are divided into much smaller holes
Slip planes for BBC
Same as CCP (12) equally ductile
Face Centered Cubic (FCC)
arrangement of atoms, doesn’t describe if atoms are in contact
CPP always FCC
FCC not always CPP
Close-Packed structure of silicon and diamond
FCC Crystal
Graphite
ABABABAB
electrical conductor in planes
electrical insulator in perpendicular position
=anisotropic
anisotropic
different properties in different directions
Steric Hindrance
when chemical groups get in the way of others and prevent a neat arrangement