Chp. 14: Polymers are not just plastic Flashcards
Elastomer
a polymer that can be stretched by large amounts and return to its original length, like rubber.
Thermoplastic
a polymer that becomes soft when heated and then can be shaped, then becomes rigid in that shape once it cools., like polyethylene.
Thermosets
a polymer that becomes more rigid when heated.
Crosslinking
using atoms such as oxygen and sulfur which insert bridges between chains and thus inhibit their slider over each other
Vulcanization
adding sulfur to rubber to make it stronger
ebonite
when so much sulfur is added to rubber, it becomes a rigid black solid, like clarinets.
Chain Stiffening
by replacing atoms with large side groups, to inhibit bonds from rotating and also to roughen the chains to make it more difficult for them to move past each other
Steric Hindrance
Large groups of atoms block an atom in a polymer from rotating, making it stiffer.
Chain crystallization
packs the chains very close together over long distances thus increasing the bond strength between them and therefore strengthening them
mers
the individual units of a poly”mer”