chp 3 general chem DAT Flashcards
the octet rule
all elements want to feel like a noble gas because all noble gases have their octet electrons
ion and shifting
when an atoms gains an electron they become negative charged -ANIONS
when an atom loses an electron they become positively charged -CATIONS
losing and gaining shifting
losing - shifts to column to the right
gain - shift back a column so to the left
2 types of compounds
ionic = metal and nonmetal
molecular = 2 or moe nonmetals
ionic compounds
the metal gives the nonmetal its electron , the metal becomes the cation and nonmetal is anion
ionic exceptions
these ionic compounds are made of only nonmetals (polyatomic ions)
molecular compounds
2 or more nonmetals . the bonds between these nonmetals are covalent bonds . in the covalent bonds the atoms share their electrons resulting in partial neg or pos
polar covalent
are when molecular compounds that have an UNEVEN sharing of electrons. they have partial neg and pos
non polar covalent
this occurs when nonmetal bonded to atoms do NOT have a significant electronegativity - they do not have partial neg and pos
ionic compound
HIGH melting point ,HIGH boiling point , brittle and hard
ionic interactions
molecular compound
LOW melting point , do not conduct electricity
intermolecular forces
network covalent
HIGH melting point , HIGH boiling point , hard,do not conduct electricity
network of covalent bonds
metallic
variable hardness and melting points , conducts electricity, conducts heat , shiny , malleable and ductile
metallic bonding
what is lattice energy ?
its the energy required to completely separate an ionic compound’s CATIONS and ANION
formula for lattice energy
LE=(cation charge ) X (anion charge ) / bond distance
bigger charges
larger lattice energy
shorter bond distance
larger lattice energy
atomic sizes -
get smaller as you go up and right same as electronegativity
how to draw a lewis structure -
- count all the electrons in each atom
-add or sub for charges
-write the least electronegative atom in the center (NEVER H )
-use electrons to fill the octet rule
make sure each element has 8 electrons If not use lone pairs or double , triple bonds
EXCEPTIONS for electrons
H only needs 2 NOT 8
Be needs 4 Not 8
B and Al sometime only have 6 electrons
sigma and pi bonds
a sigma bond single bond = all double bonds have 1 sigma and 1 pi bond
triple bonds have 1 sigma and 2 pi
formal charge
(valence electrons)-(one for each dot)-(one for each bond)
bond order -
is the average length when many different lewis structure are possible
orbital hybridization
“things around the atom”
number of things -
2=sp linear shape
3=sp2 trigonal planar or bent
4=sp3 tetreahedral , trigonal pyramid, bent
5 = sp3d trigonal bipyramid , see saw , t shape
6=sp3d2 octahedral , square pyramid and square planar
non polar vs polar
OH bonds are polar
CH bonds are non polar