chemistry - identifying ions Flashcards

1
Q

how do you carry out a flame test to identify metal ions?

A
  • clean a platinum wire loop by dipping it in HCl and then holding it in the blue flame until it burns without any colour
  • dip the loop into the sample you want to test and place into the blue flame of a bunsen burner
  • record the colour change
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2
Q

what is each result of a flame test?

A

lithium - crimson red
sodium - yellow
potassium - lilac
calcium - orange/red
copper (2+) - green

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3
Q

what is the acronyms to remember the flame tests?

A

ions: Lively Snakes Paint Colourful Chickens
colours: Crazy Yellow Lions Offer/Real Greatness

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4
Q

how to test for carbonate ions?

A
  • add a few drops of HCl to the sample in a test tube
  • connect this test tube to a test tube of limewater (calcium hydroxide)
  • if carbonate ions are present, the limewater will turn cloudy, as carbon dioxide is produced
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5
Q

how to test for sulphate ions?

A
  • add HCl to remove any other ions as this will impact the results
  • add barium chloride
  • if sulphate ions are present, a white precipitate is formed
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6
Q

how to carry out a test for halide ions?

A
  • add a couple drops of nitric acid to react any carbonate ions that are present
  • add a few drops of silver nitrate
  • observe the colour of the precipitate
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7
Q

what is the colour of each precipitate when silver nitrate is added to a bromide solutions?

A

chloride ions - white
bromide ions - cream
iodide ions - yellow

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8
Q

what colour precipitate forms when sodium hydroxide reacts with calcium ions?

A

white precipitate

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9
Q

what colour precipitate forms when sodium hydroxide reacts with copper (II) ions?

A

blue precipitate

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10
Q

what colour precipitate forms when sodium hydroxide reacts with iron (II) ions?

A

green precipitate

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11
Q

what colour precipitate forms when sodium hydroxide reacts with iron (III) ions?

A

brown precipitate

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12
Q

what colour precipitate forms when sodium hydroxide reacts with aluminium ions?

A
  • white precipitate at first
  • redissolves with excess NaOH to form a colourless solution
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13
Q

what colour precipitate forms when sodium hydroxide reacts with magnesium ions?

A

white precipitate

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14
Q

given two solutions, how can you identify which contains aluminium ions and which contains magnesium ions?

A
  • add excess sodium hydroxide
  • both will form white precipitates but the one containing aluminium ions will redissolve to form a colourless solution
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