Chemistry chapter 6 (Electrochemistry) Flashcards

1
Q

Define conductors?

A

Materials capable of carrying electric current, materials which have “Mobile charge carriers”

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2
Q

Define Insulators?

A

Materials with no or very few free charge carriers

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3
Q

Define electrolysis?

A

The process by which an electric current flows through a liquid compound or solution to cause a chemical reaction.

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4
Q

Is there a chemical reaction when Electric current passes through a metal or graphite?

A

No

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5
Q

Define Electrolyte?

A

substances that dissolved in water produces a solution that conducts electricity

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6
Q

What do electrolytes contain?

A

ions

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7
Q

Define Nonelectrolyte?

A

A substance that dissolved in water produces a solution that does not conduct electricity

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8
Q

Examples of electrolytes?

A

. Molten salts
. Solutions of salt in water
. Solutions of acid
. Solutions of alkalis

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9
Q

Examples of Non-electrolytes?

A

. Distilled water
. Ethanol
. Petrol
. Paraffin
. Sugar solution

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10
Q

Difference between conduction of electricity in solid/liquid metals and solution?

A

In metals and liquid metals, the electricity is conducted through electrons, while in solutions the electricity is conducted through movement of ions.

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11
Q

How does electrolysis work?

A

Electric current flows through the positive electrode (Anode), negative ions of the solution (anion) travel to anode and loose electrons, and are transformed into neutral molecules. The positive ions of the solution (Cation) are attracted to the negative electrode (Cathode), gain electrons and are transformed into neutral molecules.

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12
Q

Properties of electrolytic conductivity?

A

. Ions flow
. Takes place is liquids and solutions (Not solids)
. Chomical decomposition takes place

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13
Q

Characteristics of metallic conductivity?

A

. Electrons flow
. Takes place in solids and liquids (liquid metals)
. No chemical change takes place

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14
Q

Define electrolytic cell?

A

The apparatus in which the electrolysis is carried out

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15
Q

Define Electrode?

A

Rods that carry the current into and out of the solution/liquid

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16
Q

Define Cathode?

A

negatively charged Electrode

17
Q

Define cation?

A

Positively charged ions

18
Q

Define Anode?

A

Positevly charged electrode

19
Q

Define Anion?

A

Negatively charged ions

20
Q

Examples of uses for sodium?

A

Sodium can be used in street lamps and as a coolant in some nuclear reactors.

21
Q

Define selective discahrge?

A

When the ions move to the anode and cathode, only one negative and one positive ion will be selected to be discharged

22
Q

How is selective discharge decided?

A

It is according to the reactivity series (for cations) and the Electrochemical series (for anions) as less reactive ions are easier to oxidize

23
Q

Factors affecting selective discharge?

A

. Position in reactivity series
. The concentration
. The type of electrode used

24
Q

Define a half equation?

A

the reaction at each electrode

25
Q

Describe how concentration may affect selective discharge?

A

If the concentration of a particular ion is high, it may be selected to be discharged even though it is higher in the electrochemical series.

26
Q

What happens if the negative ion is complex (NO3, SO4) compared to simple (Cl, Br)

A

If the negative ion is simple then that element will be produced, if it is complex however oxygen from the OH will be produced instead

27
Q

What are the 2 types of electrodes?

A

Inert Electrode and Active electrode

28
Q

Define Inert electrode?

A

Inert electrodes do not react with electrolyte and does not take part in the reaction. (Graphite, Platinum)

29
Q

Define Active electrode?

A

Active electrode will react with the electrolyte and take part in the reaction. (Copper, Gold, Mercury)

30
Q

Define dilute?

A

A concentration that has more solvent than solute

31
Q

Define concentrated?

A

Solution that contains more solute than solvent

32
Q

Define Molten?

A

melted into liquid (No presence of water)

33
Q

Electrolytic cell compared to Electrochemical cell?

A

Electrolytic cell: Electrical energy to chemical energy
Electrochemical cell: Chemical energy to Electrical energy

34
Q

What is the efficancy of hydrogen fuel compared to petrol?

A

Hydrogen has a 60% efficiency compared to 35% for petrol

35
Q

How is hydrogen for fuel obtained?

A

Through electrolysis of water

36
Q

Disadvantages of hydrogen fuel?

A

. A large fuel tank required
. Very few stations to top off
. Engine redesign needed
. Currently expensive
. Non-renewable if generated using nuclear energy or fossil fuels

37
Q

Advantages of hydrogen for fuel?

A

. Renewable if produced using solar energy
. Lower flammability
. Virtually emission free
. Non-toxic
. Does not produce C02

38
Q

Explain a test for chlorine?

A

By placing blue litmus paper in the gas container, the Litmus paper turns red and then colorless.