CHEMISTRY C6: RATES OF REACTION Flashcards
what are the main factors that affect the rate of chemical reactions?
-increasing the concentrations of dissolved reactants increases collisions and the RoR
-increasing pressure is the same as increasing concentration
-increasing temperature raises the frequency of collisions, therefore the RoR increases
-increasing the surface area increases collisions and RoT
-catalysts are used up substances the increase RoR without being used up in the process
catalysts aren’t used up in chemical reactions. what does this mean?
-they can be used indefinitely
-they are not found in chemical equations
(they need to be cleaned often - having knock-on environmental impacts
different reactions need different catalysts. Here are some examples:
-iron is used in the process to make ammonia
-platinum and palladium are used as catalytic converters in cars
-enzymes catalyse reactions in biological systems
why do catalysts often come as powders, pellets or fine gauzes?
these types of substances all have particularly high surface areas
what do catalysts lower in reactions?
all catalysts lower the activation energy needs in a reaction
catalysts advantages - cost effective
-only a small amount of the catalyst is needs to speed up the reaction a lot
-paying for the catalyst may be cheaper than paying for the energy needed to increase temperature or pressure
catalysts advantages - reduced burning of fossil fuels
-by reducing the necessary temperature or pressure, fewer fossil fuels need to be burnt
catalysts disadvantage- toxicity
-many are toxic and can escape into the environment and contaminate ecosystems
what are the factors that affect rates of reaction?
-temperature
-concentration
-particle size
-use of a catalyst
what happens when temperature is increased?
if the temperature is increased, the particles have more energy meaning they will move much quicker. RoR increases as the collide more often
what happen when concentration is increased?
when the concentration of reactants are increased there will be more particles; and collisions will occur more often, increasing RoR
what happens when the particle size is increased?
when a particle’s size is decreased, it increases it’s surface area; causing more collisions and then the RoR will be increasd
what happens when a catalyst is used?
a catalyst increases the rate of reaction but isn’t used up. when a catalyst is present, the reacting particles collide more successfully
how do you calculate the rate of reaction?
to measure the average rate:
change in quantity average rate = ————————— change in time