Chemistry A2 - Acids, Buffers, and Bases Flashcards
What is a Bronsted acid?
A species which can donate a proton
What is an example of a Bronsted aicd?
HCl
What is a Bronsted base?
A species which can accept a proton
What is an example of a Bronsted base?
A hydroxide ion (OH-)
Define a weak acid
One which only partially dissociates in solution
What is an example of a weak acid?
Ethanoic acid (CH3COOH)
What are monobasic/monoprotic acids?
Acids which contain one ionisable hydrogen atom in each molecule, HCl, for example
What are dibasic/diprotic acids?
Acids which contain two ionisable hydrogen atoms per molecule, H2SO4, for example
What are tribasic/triprotic acids?
Acids which contain three ionisable hydrogen atoms per molecule, H3PO4, for example
Acid + metal –> ?
Salt + hydrogen
Acid + metal oxide –> ?
Salt + water
Acid + metal carbonate –> ?
Salt + water + carbon dioxide
Acid + alkali –> ?
Salt + water
What is the overall expression for Ka?
[H+][A-] / [HA]
What can we tell about an acid if it has a higher Ka value?
It is a stronger acid - the higher the value, the more dissociated the acid and the stronger it is
How do we calculate pKa?
-log(Ka)
How do we calculate pH?
-log[H+]
How do we calculate the concentration of H+ when we know the pH of the solution?
10^ -pH
What is the equation for the ionic product of water (Kw)?
[H+][OH-]
How do we find the Ka for a weak acid experimentally?
- Prepare a standard solution of the weak acid of known concentration
- Measure the pH of the standard solution using a pH meter
- Do some calculations to find Ka
What are two approximations we make when carrying out calculations which involve weak acids?
- The concentrations of H+ and A- are equal
- The dissociation of water is negligible
What is the importance of Kw?
It sets up the value for the neutral point on the pH scale
What is the [H+] and [OH-] in an acid solution with a pH of 3?
[H+] = 10^-3
[OH-] = 10^-11
What is a buffer solution?
A solution which resists changes in pH when small amounts of acids or alkalis are added