chemistry - 1.1 Flashcards

1
Q

How can electromagnetic radiation be described?

A

In terms of waves and characterised in terms of wavelength and/or frequency.

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2
Q

What is the relationship between wavelength, frequency and speed of light?

A

c = f lambda

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3
Q

What is known as the electromagnetic spectrum?

A

The different types of radiation arranged in order of wavelength.

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4
Q

What are wavelengths of visible light normally expressed in?

A

Nanometres.

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5
Q

What can electromagnetic radiation be described as?

A

A wave (has a wavelength and frequency), and as a particle, and is said to have a dual nature.

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6
Q

When electromagnetic radiation is absorbed or emitted by matter, what does it behave like?

A

A stream of particles - known as photons.

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7
Q

What does a photon carry?

A

Quantised energy proportional to the frequency of radiation.

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8
Q

What happens when a photon is absorbed or emitted?

A

Energy is gained or lost by electrons within the substance.

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9
Q

What can photons in high frequency radiation transfer?

A

Greater amounts of energy than photons in low frequency radiation.
The energy associated with a single photon is given by:

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10
Q

What is the energy associated with a single photon given by?

A

E=hf or E=hc/lambda

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11
Q

What is the energy associated with one mole of photons given by?

A

E=Lhf o rE=Lhc / lambda

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12
Q

What units is energy often given in?

A

kJ mol-1

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13
Q

When energy is transferred to atoms, what may happen to electrons within the atoms?

A

They may be promoted to higher energy levels.

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14
Q

When does an atom emit a photon of light energy?

A

When an excited electron moves from a higher energy level to a lower energy level.

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15
Q

What does the light energy emitted by an atom produce?

A

A spectrum that is made up of a series of lines at discrete (quantised) energy levels. This provides direct evidence for the existence of these energy levels.

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16
Q

What does each element in a sample produce and what can these be used for?

A

Characteristic absorption and emission spectra. These spectra can be used to identify and quantify the element.

17
Q

In absorption spectroscopy, what is electromagnetic radiation directed at?

A

An atomised sample. Radiation is absorbed as electrons are promoted to higher energy levels.

18
Q

How is an absorption spectrum produced?

A

By measuring how the intensity of absorbed light varies with wavelength.

19
Q

In emission spectroscopy, what is used to excite the electrons within atoms?

A

High temperatures.

20
Q

As the electrons drop to lower energy levels, what happens?

A

Photons are emitted.

21
Q

How is an emission spectrum of a sample produced?

A

By measuring the intensity of light emitted at different wavelengths.

22
Q

In atomic spectroscopy, what is the concentration of an element within a sample related to?

A

The intensity of light emitted or absorbed.