Chemical tests - TN Flashcards
test for hydrogen
burn it in oxygen
hear a squeaky pop
why is a squeaky pop heard when hydrogen is burnt in oxygen
all the hot gas rushing out of the test tube
test for oxygen and why
a glowing splint relighting - the oxygen in the tube is more concentrated than in normal air so the wood in the splint combusts faster
how to test for the presence of water
anhydrous copper sulfate turning white to blue
how to test the purity of water
measure its boiling point - 100*C
closer to 100*C = more pure
test for carbon dioxide and why
bubble it through limewater - limewater is a saturated calcium hydroxide solution. it forms a white precipitate of calcium carbonate when it reacts with CO2
test for chlorine
damp (the cl dissolves into the H2O) blue litmus turning blue to white - cl is a bleaching agent so it removes the colour.
test for ammonia and why
damp red litmus turning red to blue
NH3 reacting with the H2O to form OH- ions which are alkaline = blue colour
what is a cation
a positive ion
what kind of flame is needed on a Bunsen burner in order to carry out a flame test
a non-luminous (blue) flame
3 steps to conduct a flame test
- dip a piece of nichrome/platinum wire into hydrochloric acid (these wires don’t colour the flame and the acid cleans the wire)
- dip the wire into a sample of solid or solution
- place the tip of the wire into a non-luminous bunsen flame
flame test colour of lithium
red
flame test colour of sodium
yellow
flame test colour of potassium
lilac
flame test colour of calcium
orange-red
flame test colour of copper
blue-green
how to test for copper without using a flame test
sodium hydroxide solution with a blue precipitate forming
how to test for iron (II)
sodium hydroxide solution with a green precipitate forming
how to test for iron (III)
sodium hydroxide solution with a brown precipitate forming
how to conduct a sodium hydroxide test
- dissolve the sample in water
- add a few drops of NaOH
how to test for ammonium (NH4)
sodium hydroxide solution - creates a gas that turns damp red litmus paper from red to blue
chemical formula of ammonia
NH3
chemical formula of ammonium
NH4
what are the 3 steps for testing ammonium
- dissolve the sample in water
- add some NaOH and warm it
- test the gas evolved with damp red litmus paper (ammonia test)
it NH4 ions are present the paper will turn blue
what is an anion
a negatively charged ion
how to test for halides
silver nitrate test
what are the 3 steps of the silver nitrate test
- dissolve the sample in water
- add nitric acid
- add silver nitrate solution
is cl, br, or i ions are present, a precipitate forms with the Ag ions from the AgNO
during a silver nitrate test for halide ions: what colour does Chloride turn
white precipitate
during a silver nitrate test for halide ions: what colour does bromide turn
cream precipitate
during a silver nitrate test for halide ions: what colour does iodide turn
yellow precipitate
why do you add nitric acid first when performing a silver nitrate test
because the Ag ions that we need to react with the halides, also react and forms precipitates with other anions such as OH- and CO3. the HNO3 reacts with those anions preventing false positives
how to test for carbonates
- add hydrochloric acid, look for effervescence
- if there is effervescence, bubble the gas through limewater
if a carbonate is present, the limewater will turn cloudy
why do we bubble the gas created (during a test for carbonates) through limewater
to test if the gas is actually CO2 because acids also evolve a gas when they react with some other things. this prevents false positives
test for sulfates
- add hydrochloric acid, look for effervescence
- if there is no effervescence, add barium chloride solution
is SO4 ions are present they will form a WHITE PRECIPITATE wiht the Ba ions from the BaCl
during a test for sulfates, why do we first add hydrochloric acid
because carbonates also form a white precipitate with Ba ions. by only continuing to step 2 if there is no effervescence (the test for carbonates), we can prevent a false positive