Chemical Bonding Flashcards

0
Q

Forces between molecules , weaker than between atoms

A

Intermolecular forces

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1
Q

Atoms in molecules are held together by chemical bonds which are also called

A

Intramolecular bonds

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2
Q

How many valence electrons can hydrogen and helium have ?

A

2

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3
Q

How many valence electrons can lithium have?

A

2

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4
Q

How many valence electrons can beryllium have ?

A

4

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5
Q

How many valence electrons can boron have ?

A

6

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6
Q

Beyond the _ row, elements can expand their Octets to more than 8 electrons

A

2nd

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7
Q

Form crystal lattices, have high melting and boiling points, conduct electricity except in solid state

A

Ionic compounds

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8
Q

Low melting points, do not conduct electricity , weak intermolecular forces

A

Covalent compounds

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9
Q

The number of shared electron pairs between two atoms

A

Bond order

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10
Q

As bond length increases, bond energy ?

A

Decreases

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11
Q

Increase in number of shared electrons caused a ____ in bond length

A

Decrease

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12
Q

The energy required to separate two bonded atoms. This increases as the number of shared electrons increases.

A

Bond energy

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13
Q

Formal negative charge should go on the most _______ atom

A

Electronegative

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14
Q

A dipole moment is measured in vector quantity u measured in ____ units

A

Debye (coulomb-meters)

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15
Q

Dipole moment equation

A

U= q(product of charge magnitude) x r(distance between two partial charges)

16
Q

In this type of bond the shared electron pair come from the lone pair of one of the atoms in the molecule

A

Coordinate covalent bond

17
Q

Compound that can accept an electron pair to form a covalent bond

A

Lewis acid

18
Q

Compound that can donate an electron pair to form a covalent bond

A

Lewis base

19
Q

Structure that has 4 electron pairs and no nonbonding pairs

A

Tetrahedral(109.5)

20
Q

4 electron pairs , 1 non bonding pairs

A

Trigonal pyramid

21
Q

4 electron pairs , 2 non bonding pairs

A

Bent (104.5)

22
Q

5 electron pairs no non bonding pairs

A

Trigonal bipyramidal (90,120,180)

23
Q

6 electron pairs , no non bonding pairs

A

Octahedral (90,180)

24
Q

3 electron pairs , no nonbonding pairs

A

Trigonal pyramid (120)

25
Q

If the sign of two overlapping orbitals are the same, what is formed ?

A

A bonding orbital

26
Q

If the signs of two atomic orbitals overlapping are different , what is formed?

A

An anti bonding orbital

27
Q

When two orbitals of different atoms overlap head to head , what is formed ?

A

A sigma bond

28
Q

When paralleled p orbitals interact, what is formed ?

A

A pi bond

29
Q

What is the order in decreasing strength for the intermolecular forces ?

A

Ionic bonds (dipole-ion) > hydrogen bonding > dipole-dipole > LDF

30
Q

Hydrogen bonding occurs even hydrogen is bound to either?

A

Fluorine oxygen nitrogen

31
Q

What kinds of compounds are drawn into a magnetic field ?

A

Paramagnetic molecules. These are any compound having an odd number of valence electrons.

32
Q

What two elements with hydrides contain incomplete Octets?

A

Be and B because they can join to only two or three H respectively and they have fewer than 4 electrons. Mg, Al may also do this as well as Na,Ca and other active metals of groups 1A and 2 A