Chemical analysis and electolysis Flashcards

1
Q

What are flame tests used for?

A

Identifying metal ions

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2
Q

Lithium flame

A

crimson

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3
Q

Sodium flame

A

Yellow

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4
Q

Potassium flame

A

Lilac

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5
Q

Calcium flame

A

Red

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6
Q

Barium flame

A

Green

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7
Q

How do you flame test a compound?

A

dip a clean wire loop into a sample of the compound and put the wire loop in the clear blue part of bunsen flame
Make sure the loop is clean by dipping it into HCl and rinsing with distilled water

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8
Q

Chlorine gas test

A

bleaches damp litmus paper, turning it white (may turn red because chlorine solution is acidic)

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9
Q

Test for oxygen

A

relighting a glowing splint

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10
Q

Test for hydrogen

A

squeaky pop with lighted splint (comes from hydrogen burning with the oxygen in the air to form H2O)

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11
Q

What do you do if the flame test for metals doesn’t work?

A

some metals form a coloured precipitate with NaOH

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12
Q

Calcium hydroxide

A

white

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13
Q

copper hydroxide

A

blue

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14
Q

Fe(OH)2

A

green

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15
Q

Fe(OH)3

A

brown

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16
Q

aluminium hydroxide

A

white at first. then dissolves and goes colourless

17
Q

Magnesium hydroxide

A

White

18
Q

CO2 test

A

bubble through limewater turns cloudy,

test for carbonates

19
Q

Halide test

A
different precipitates formed,
add dilute nitric acid and the silver nitrate solution
chloride white
bromide cream
iodide yellow
20
Q

Sulfate test

A

dilute HCl and dilute barium chloride solution

white precipitate

21
Q

Mobile phase

A

where molecules can move, liquid or gas

22
Q

stationary phase

A

where molecules can’t move, solid or thick liquid

23
Q

How does chromatography work?

A

dynamic equilibrium between mobile and stationary phase, chemical separate out and travel at different speeds

24
Q

Paper chromatography

A

chemicals dissolve in solvet (ethanol or water) and move in dynamic equilibrium between paper and solvent
the chemicals that spend more time in the mobile phase form spots further up the paper

25
Q

What does the amount of time spent in each phase depend on in paper chromatography?

A

how soluble molecules are

how attracted they are to the paper

26
Q

stationary phase in TLC

A

silica gel spread onto a glass plate

27
Q

What is the result of chromatography analysis called?

A

chromatogram

28
Q

What happens if chromatography spots are colourless?

A

locating agent

29
Q

What is an Rf value?

A

ratio between distance travelled by solute and distance travelled by solvent

30
Q

Rf formula

A

distance travelled by solute/distance travelled by solvent

31
Q

Phenophthalein

A

pink alkali

colourless in acids

32
Q

Methyl orange

A

yellow alkali

red acids

33
Q

Electrolysis of lead bromide

A

molten

negative electrode accepts two electrons to become one lead atom etc

34
Q

Electroplating

A

uses electrolysis to coat the surface of one metal with another metal
metal ions travel to cathode and electrode gains mass