Chem-Phys (new) Flashcards
What is the equation for half life?
N(t) = N_0 (1/2)^(t/t_1/2})
N(t) = quantity of the substance remaining N_0 = initial quantity of the substance t = time elapsed t_{1/2} = half life of the substance
How do you solve a fraction of a power?
fractions of powers
What does mass number (superscript) refer too?
superscript refers to mass number (number of protons and neutrons)
If a cell is placed in an environment with higher solute concentration than inside the cell, is it hypertonic or hypotonic?
If a cell is placed in an environment that contains a higher concentration of solutes than the interior of the cell, we call this environment hypertonic. When a cell is placed in a hypertonic solution, the solution is relatively solute-rich, while the cell is relatively watery. Therefore, water will move from the cell into the surrounding solution to equalize the solute concentration. This will cause the cell to lose water and shrink. In contrast, when a cell is exposed to a hypotonic (lower in solute concentration) environment, water will travel from the environment into the cell, causing the cell to swell and even burst, or lyse. Finally, an environment with the same solute concentration as the cell in question is termed isotonic.
what happens to a liquid when the vapor pressure is equal to the atmospheric pressure?
When vapor pressure is equal to the atmospheric pressure exerted on the liquid’s surface, the liquid will boil. The more solute particles present, the lower the vapor pressure, and the higher the boiling point.
What do the suffixes -ous and -ic in an ionic compund mean?
The ion with the lesser charge will use the suffix “-ous,” and the ion with the greater charge will use the suffix “-ic.” For example, the iron (II) cation, Fe2+, is termed the ferrous ion, while the iron (III) cation, Fe3+, is the ferric ion
What do gamma rays represent?
Paragraph 3 mentions that the nuclei emit gamma rays, a form of electromagnetic radiation that consists of high-energy photons. Gamma rays represent ionizing radiation. The passage also states that I-131 undergoes β-minus decay. In β-minus decay, a neutron is converted to a proton as an electron is emitted. Therefore, iodine must be converted to an element with one additional proton, which can only be Xe
How would you separate an acidic compound from a neutral one? (answer: extraction)
If all are liquids, one may be able to utilize distillation, which aims to separate liquids by utilizing the difference between their boiling points. If boiling points are very high, a vacuum may also be used to lower atmospheric pressure, which lowers the boiling points of all substances involved. Recrystallization is used to purify a solid product that contains impurities. Chromatography is a broad set of separatory techniques based on relative affinity, or tendency for a compound to attract to a certain solvent or structure. Finally, centrifugation utilizes a rapidly spinning apparatus to separate particles by density.
What is the purpose of boiling chips? What is the purpose of vacuum distillation?
Boiling chips are used to provide nucleation sites that give the liquid a place to start forming bubbles to prevent superheating. Vaccum distillation lowers the boiling points of the substances to be distilled.
What is the structure of (blank) functional group? (for all of them)
Know the structures of the functional groups
What is the equation for kinetic energy?
KE = ½ mv2
What is a tetrahedral stereocenter?
tetrahedral stereocenter = chiral center
What is the equation for torque?
torque: τ = rFsin(Ɵ). Thus, there are three ways to increase the torque applied to an object: (1) increasing the force, (2) increasing the distance at which the force is applied from the fulcrum, and (3) adjusting the angle at which the force is applied to make it as close as possible to perpendicular to the lever arm.
What is the equation for average velocity?
average velocity: v = d/t
What does the equivalence point of a titration represent?
At equivalence points during the titration, the number of acid or base groups added to the solution is equivalent to the number of base/acid groups in the original unknown solution. We can calculate our unknown concentration or volume using the formula NaVa = NbVb, where N and V are the normality (mol/L) and volume of the acidic and basic solutions, respectively. It is important to convert from molarity (M) to normality (N) for polyprotic acids and polyvalent bases.
What do Km and Vmax represent? What is the difference between competetive, noncompetetive, and uncompetetive inhibition?
Competitive inhibitors increase the Km of their associated enzymatic reactions without altering the Vmax value. Study Michaelis-Menten graphs
What is the relationship between Ka pKa and pH?
Ka = [H+][A−]/[HA]
What are Newtons 3 laws?
Newton’s third law can be expressed as: FA on B = −FB on A. Newton’s first law is a statement about inertia. It states that within a reference frame, an object remains at rest or at a constant velocity unless an external force acts upon it. Newton’s second law defines force. It states that the total sum of forces acting on an object is equivalent to its mass times its acceleration. This is the familiar equation Fnet = ma.
What is the bond angle of a trigonal planar molecule?
Tetrahedral molecules contain four electron-rich areas and four bonded atoms, at angles of 109.5°. Trigonal pyramidal molecules likewise have four electron-rich areas, but only three are bonded atoms and the fourth is a lone pair. Bent molecules, like H2O, have two bonded atoms and two lone pairs. The bond angles in trigonal pyramidal molecules and bent molecules (107° and 104.5°, respectively) are slightly smaller than the 109.5° angle found in tetrahedral molecules. Trigonal planar molecules, like BF3, have three electron-rich areas and three bonded atoms at 120° angles, and linear molecules, such as CO2, have two electron-rich areas and two bonded atoms. Trigonal bipyramidal (e.g. PCl5) and octahedral molecules (e.g. SF6) have five and six electron-rich areas, respectively.
How do you calculate resistance for resistors in series? In parallel? What is the equation for power?
Circuits can contain multiple resistors, which can be connected either in parallel or in series. For a circuit with resistors R1, R2, … Rn wired in series, Itotal = I1 = I2 = … = In, Vtotal = V1 + V2 + … + Vn, and Rtotal = R1 + R2 + … + Rn. If the resistors are wired in parallel, Itotal = I1 + I2 + … + In, Vtotal = V1 = V2 = … = Vn, and 1/Rtotal = 1/R1 + 1/R2 + … + 1/Rn.
What are stong oxidizing agents? What are strong reducing agents?
The following features are associated with reduction in organic chemistry: (1) gain of an electron, (2) decreased oxidation state, (3) formation of a C–H bond (e.g. alkene → alkane), and (4) loss of a C–O or C–N bond (or any bond between carbon and an electronegative atom). Conversely, oxidation is associated with (1) loss of an electron, (2) increased oxidation state, (3) loss of a C–H bond (e.g. alkane → alkene), and (4) gain of a C–O or C–N bond (or any bond between carbon and a highly electronegative atom). A strong reducing agent, such as LiAlH4, can reduce a carboxylic acid directly to an alcohol, while weak reducing agents such as NaBH4 will not reduce carboxylic acids at all.
What are the six primary classes of enzymes and what reactions do each carry out?
Oxidoreductases catalyze oxidation-reduction reactions where electrons are transferred. Transferases catalyze transfer of a chemical group from one molecule (donor) to another (acceptor). Lyases catalyze reactions where functional groups are added to break bonds in molecules or they can be used to form new double bonds or rings by the removal of functional group(s). Hydrolases catalyze reactions that involve cleavage of a molecule using water (hydrolysis). Ligases are used in catalysis where two substrates are stitched together (i.e., ligated) via the formation of C-C, C-S, C-N or C-O bonds while giving off a water (condensation) molecule.
Where are the hydroxyl and carbonyl peaks on an IR spectroscopy graph?
The main peaks of an IR spectroscopy graph
Between what side chains are disulfide links bonded? Why?
Disulfide linkages only form between the side chains of cysteine (C) residues.