Chem Flashcards

1
Q

Assumes the volume and the shape of its container

A

gas

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2
Q

Density - Low
Compressibility - Very Compressible
Motions of molecules - Very free motion

A

gas

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3
Q

Has a definite volume but it assumes the shape of its container

A

Liquid

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4
Q

Density - High
Compressibility - Only slight compressible
Motions of molecules - Slide past one another freely

A

Liquid

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5
Q

Has a definite volume and shape

A

Solid

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6
Q

Density - High
Compressibility - Virtually compressible
Motions of molecules - Vibrate about fixed positions

A

Solid

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7
Q

attractive forces between molecules.

A

Intermolecular forces

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8
Q

hold atoms together in a molecule.

A

Intramolecular forces

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9
Q

Intermolecular vs. Intramolecular

A
  • Intramolecular forces stabilize individual
    molecules, whereas intermolecular
    forces are primarily responsible for the
    bulk properties of matter.
  • In general, intermolecular forces are
    much weaker than intramolecular forces.
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10
Q

Do not have ONE distinct
positive end or ONE
distinct negative end.

The whole molecules
has often multiple
charges but without
“poles”

A

NONPOLAR
MOLECULES

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11
Q

ONE distinct positive
end

ONE distinct
negative end make a
molecular polar

A

POLAR MOLECULES

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12
Q

All of the attractive forces between natural atoms and molecules are also known as

A

Van Der Waals forces

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13
Q

the amount of energy
required to stretch or increase the surface of a
liquid by a unit area.

A

Surface Tension

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14
Q

the intermolecular attraction between like molecules.

A

Cohesion

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15
Q

attraction between unlike molecules.

A

Adhesion

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16
Q

a special dipole – dipole
interaction between they hydrogen atom in a
polar N -H, O-H, or F-H bond and an
electronegative F, O, or N atom

A

hydrogen bond

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17
Q

the measure with which the electron distribution in the atom or molecule can be distorted.

A

Polarizability

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18
Q

forces are attractive forces between an ion and a polar molecule. The strength of this interaction depends on the charge and size of the ion and on the magnitude of the dipole moment and size of the molecule.

A

Ion-dipole

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19
Q

attractive forces between polar molecules. The larger the dipole moment, the greater the force.

A

Dipole – dipole forces

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20
Q

a measure of a fluid’s resistance to
flow. It depends on intermolecular forces and on the shape of molecules

A

Viscosity

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21
Q

possesses rigid and long – range order. In a crystalline solid, atoms, molecules or ions occupy specific (predictable) positions.

A

crystalline solid

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22
Q

does not possess a well – defined arrangement and long – range molecular order.

A

amorphous solid

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23
Q

the basic repeating unit structural
unit of a crystalline solid.

A

unit cell

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24
Q

the upward or downward curve at the surface of a liquid

A

meniscus

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25
* Lattice points occupied by molecules * Held together by intermolecular forces * Soft, low melting point * Poor conductor of heat and electricity.
Molecular Crystals
26
* Lattice points occupied by atoms * Held together by covalent bonds * Hard, high melting point * Poor conductor of heat and electricity
Covalent Crystals (or Network)
27
* Lattice points occupied by cations and anions * Held together by electrostatic attraction * Hard, brittle, high melting point. * Poor conductor of heat and electricity.
Ionic crystals
28
* Lattice points occupied by metal atoms * Held together by metallic bonds * Soft to hard, low to high melting point * Good conductors of heat and electricity
Metallic crystals
29
Ionic Bond | Hard, high melting point, poor conductor of heat and electricity
Ionic
30
Covalent Bond | Hard, high melting point, poor conductor of heat and electricity
Covalent
31
Dipole-dipole, dipole-induced dipole, dispersion, hydrogen bond | Soft, low melting point, poor conductor of heat and electricity
Molecular
32
Metallic bond | Soft to hard, generally with high melting point, ductile, malleable, lustrous, dense, good conductor of heat and electricity
Metallic
33
is the capacity to do work
Energy
34
directed energy change resulting from a process
work or mechanical energy
35
the stored energy in an object or system due to its relative position, composition, or condition.
Potential energy
36
the energy possessed by an object or system because of its motion
Kinetic energy
37
during a chemical or physical change, energy can be neither created nor destroyed, although it can be changed in form
Law of Conservation of Energy
38
to describe the energy changes that occur during a process we often use
“heat absorbed” or” heat released”
39
a measure of the thermal energy.
Temperature
40
the transfer of thermal energy between two bodies at different temperatures
Heat (q)
41
achieved when both substances are at the same temperature, and their molecules have the same average kinetic energy
Thermal equilibrium
42
a branch of chemistry that describes the energy changes that occur during chemical reactions
Thermochemistry
43
the part of the universe that is of interest in a study in which the physical or the chemical change occurs
System
44
the part outside the system that exchanges the energy with the system in the form of heat or work.
Surrounding
45
can exchange both matter and energy with its surroundings.
open system
46
can exchange energy but not matter with its surroundings
closed system
47
exchanges neither energy nor matter with the surroundings
isolated system
48
Matter undergoing chemical reactions and physical changes can
release or absorb heat
49
any process that gives off heat – transfers thermal energy from the system to the surroundings
Exothermic process
50
any process in which heat has to be supplied to the system
Endothermic process
51
Reactions in which energy flows INTO the system as the reaction proceeds
Endothermic
52
Reactions in which energy flows OUT OF the system as the reaction proceeds
Exothermic
53
Energy can neither be created nor destroyed but can be converted between forms.
Law of Conservation of Energy
54
The total energy content of the universe is constant.
The First Law of Thermodynamics
55
depend ONLY on the present state of the system
State Functions
56
ENERGY IS A
STATE FUNCTION
57
IS NOT A STATE FUNCTION
WORK
58
VOLUME REMAINS constant is called What thermodynamic PROCESS
Isochoric process
59
NO heat transfer What Thermodynamic PROCESS
Adiabatic Process
60
Temperature remains constant What thermodynamic PROCESS
Isothermal Process
61
describes a set of technique employed to measure enthalpy changes in chemical processes using devices called calorimeters.
Calorimetry
62
Adiabatic Process no changes in
HEAT
63
PRESSURE REMAINS constant is called What thermodynamic PROCESS
Isobaric Process
64
Isochoric Process no changes in
Volume
65
Isobaric Process no changes in
Pressure
66
Isothermal Process no changes in
Temperature
67
used to quantify the heat flow into or out of a system in a process that occurs at constant pressure.
Enthalpy (H)
68
the science of heat, work, temperature, and energy, and how they affect matter and each other.
THERMODYNAMICS