CHEM 1320 Exam 1 Flashcards

1
Q

law of conservation of mass

A

sum of mass of reactants = sum mass of products

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2
Q

law of definite proportions

A

consistent with all atoms of one element are identical.

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3
Q

law of multiple proportions

A

if you double the proportions you won’t have the same out come as a single proportion

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4
Q

dalton’s atomic theory

A

1) matter is made of tiny indivisible and indestructible atoms.(conservation of mass)
2) atoms of same elements may combine in more than one ration to form 2 or more compounds(multiple proportions)
3) atoms of different elements may combine with each other in a fixed simple whole number ratios to form compounds(definite proportions)
4) all atoms of a given element are identical in mass and properties and different from other elements(incorrect)

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5
Q

medeleave

A

organized the periodic table

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6
Q

JJ Thompson

A

use cathode rays to prove that there are sub-atomic particles. (charge to mass ratio)

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7
Q

Miliken

A

oil drops experiment to show how measure the mass of an electron.

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8
Q

Rutherford

A

gold foil experiment
showed that atoms have small dense nuclei

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9
Q

electron

A

e-, light, negatively charged,

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10
Q

proton

A

p+, massive, pos charged

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11
Q

neutron

A

n, no charge, neutral

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12
Q

ions

A

when the same element has a different number of electrons

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13
Q

isotopes

A

when an atom has a different amount of neutrons

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14
Q

allotropes

A

when and element has different chemical forms (ex. carbon)

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15
Q

wavelength

A

distance between crests
units=nanometers(nm)
decides color

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16
Q

amplitude

A

measurement from line to crest
determine brightness

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17
Q

frequency

A

number of cycles that pass through a stationary point in a given time
units=hertz

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18
Q

how wavelength and frequency relate

A

as wavelength gets bigger frequency gets smaller

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19
Q

black body radiation

A

can tell how hot something is by its light color.

20
Q

planck’s theory

A

light curves in tiny packets
- more like stairs than a ramp
- Ephoton=hc/λ or hv

21
Q

photoelectric effect

A

-Albert Einstein
- photon thrown at metal releases e-
- brighter lights will emit more e-

22
Q

Niels bohr

A
  • electrons have only specific orbits and energies
  • an electron must be absorbed or evolved to move from one energy level to another
23
Q

absorbed

A

when an e- goes to a higher energy level because it ha gained energy.

24
Q

emitted

A

when an e- goes down and energy level because energy is being lost.

25
L. DeBroglie
λ=h/mv says particle has a wavelength
26
node
where amplitude of wave changes its sign
27
n
- principle quantum number - intergers (1,2,3,.., "7") - size (and energy)
28
- angular momentum quantum number - integers( 0,1,2,3,...(n-1)) - shape of orbital
29
mℓ
-magnetic quantum number - -ℓ ≤ mℓ ≤ ℓ - orientation in space (x,y,z)
30
n^2
tells the amount of possible orbitals
31
constructive interference
when 2 waves add together and make a bigger wave
32
destructive interference
when waves cancel each other out
33
diffraction
shows light has both wave nature and particle nature double slit experiment
34
ms
spin quantum number (-1/2 or 1/2)
35
s orbital
-spherical shape -ℓ=0
36
P orbitals
-dumbbell shape -ℓ=1
37
d orbitals
-clover shape -ℓ=2 -5 different values for mℓ -5 different orbitals -two nodal plaines
38
f orbitals
-ℓ=3 -3 nodal plaines -10 different values of mℓ -10 different orbitals
39
Pauli exclusion principle
no two e- can have all 4 quantum number be identical
40
scrounger equation
gives info of the energy and orbitals of e-
41
wave function Ψ
describes wave like nature of the e-
42
Ψ^2
represents an electron orbital
43
solving Schrodinger's equation for hydrogen gave following info.
-principal quantum number -angular momentum quantum number -magnetic quantum number -spin quantum number.
44
nodes
area where no probability of finding an electron
45
radial nodes
region where the radial wave function is zero.
46
angular nodes
region where angular wave function is zero.