CHEM 1320 Exam 1 Flashcards

1
Q

law of conservation of mass

A

sum of mass of reactants = sum mass of products

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2
Q

law of definite proportions

A

consistent with all atoms of one element are identical.

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3
Q

law of multiple proportions

A

if you double the proportions you won’t have the same out come as a single proportion

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4
Q

dalton’s atomic theory

A

1) matter is made of tiny indivisible and indestructible atoms.(conservation of mass)
2) atoms of same elements may combine in more than one ration to form 2 or more compounds(multiple proportions)
3) atoms of different elements may combine with each other in a fixed simple whole number ratios to form compounds(definite proportions)
4) all atoms of a given element are identical in mass and properties and different from other elements(incorrect)

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5
Q

medeleave

A

organized the periodic table

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6
Q

JJ Thompson

A

use cathode rays to prove that there are sub-atomic particles. (charge to mass ratio)

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7
Q

Miliken

A

oil drops experiment to show how measure the mass of an electron.

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8
Q

Rutherford

A

gold foil experiment
showed that atoms have small dense nuclei

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9
Q

electron

A

e-, light, negatively charged,

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10
Q

proton

A

p+, massive, pos charged

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11
Q

neutron

A

n, no charge, neutral

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12
Q

ions

A

when the same element has a different number of electrons

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13
Q

isotopes

A

when an atom has a different amount of neutrons

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14
Q

allotropes

A

when and element has different chemical forms (ex. carbon)

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15
Q

wavelength

A

distance between crests
units=nanometers(nm)
decides color

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16
Q

amplitude

A

measurement from line to crest
determine brightness

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17
Q

frequency

A

number of cycles that pass through a stationary point in a given time
units=hertz

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18
Q

how wavelength and frequency relate

A

as wavelength gets bigger frequency gets smaller

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19
Q

black body radiation

A

can tell how hot something is by its light color.

20
Q

planck’s theory

A

light curves in tiny packets
- more like stairs than a ramp
- Ephoton=hc/λ or hv

21
Q

photoelectric effect

A

-Albert Einstein
- photon thrown at metal releases e-
- brighter lights will emit more e-

22
Q

Niels bohr

A
  • electrons have only specific orbits and energies
  • an electron must be absorbed or evolved to move from one energy level to another
23
Q

absorbed

A

when an e- goes to a higher energy level because it ha gained energy.

24
Q

emitted

A

when an e- goes down and energy level because energy is being lost.

25
Q

L. DeBroglie

A

λ=h/mv
says particle has a wavelength

26
Q

node

A

where amplitude of wave changes its sign

27
Q

n

A
  • principle quantum number
  • intergers (1,2,3,.., “7”)
  • size (and energy)
28
Q

A
  • angular momentum quantum number
  • integers( 0,1,2,3,…(n-1))
  • shape of orbital
29
Q

mℓ

A

-magnetic quantum number
- -ℓ ≤ mℓ ≤ ℓ
- orientation in space (x,y,z)

30
Q

n^2

A

tells the amount of possible orbitals

31
Q

constructive interference

A

when 2 waves add together and make a bigger wave

32
Q

destructive interference

A

when waves cancel each other out

33
Q

diffraction

A

shows light has both wave nature and particle nature
double slit experiment

34
Q

ms

A

spin quantum number
(-1/2 or 1/2)

35
Q

s orbital

A

-spherical shape
-ℓ=0

36
Q

P orbitals

A

-dumbbell shape
-ℓ=1

37
Q

d orbitals

A

-clover shape
-ℓ=2
-5 different values for mℓ
-5 different orbitals
-two nodal plaines

38
Q

f orbitals

A

-ℓ=3
-3 nodal plaines
-10 different values of mℓ
-10 different orbitals

39
Q

Pauli exclusion principle

A

no two e- can have all 4 quantum number be identical

40
Q

scrounger equation

A

gives info of the energy and orbitals of e-

41
Q

wave function Ψ

A

describes wave like nature of the e-

42
Q

Ψ^2

A

represents an electron orbital

43
Q

solving Schrodinger’s equation for hydrogen gave following info.

A

-principal quantum number
-angular momentum quantum number
-magnetic quantum number
-spin quantum number.

44
Q

nodes

A

area where no probability of finding an electron

45
Q

radial nodes

A

region where the radial wave function is zero.

46
Q

angular nodes

A

region where angular wave function is zero.