Chapter 9: Atomic and Nuclear Phenomina Flashcards
Briefly describe the photoelectric effect and photosynthesis.
As a photo of light enters the chloroplast in a plant cell, it reacts with chlorophyll, causing the ejection of an electron from certain magnesium containing dyes. This electron feeds in synthetic pathways that ultimately result in glucose production. This is a primary example of the photoelectric effect.
What is the photoelectric effect?
When light of a sufficiently high frequency (typically blue to ultraviolet light) is incident on a metal in a vacuum, the metal atoms emit electrons. This is called the photoelectric effect.
Electrons liberated from the metal by the photoelectric effect will produce a net charge per unit time, or CURRENT. Provided that the light beams frequency is above the threshold frequency of the metal, light beams of greater intensity produce larger current in this way.
How is intensity of light related to the photoelectric effect?
Provided that the light beam frequency is above the threshold frequency of the metal, light beams of greater intensity produce larger currents.
The higher the intensity of the light beam, the greater the number of photons per unit time that fall on an electrode, producing a greater number of electrons per unit time liberated from the metal.
When the lights frequency is above the threshold frequency, the magnitude of the resulting current is directly proportional to the intensity (and amplitude) of the light beam.
What is the proportionality between magnitude of resulting current and intensity (and amplitude) of a light beam?
When the light frequency is above the threshold frequency, the magnitude of the resulting current is directly proportional to the intensity, and amplitude, of the light beam.
What is the proportionality between light intensity and amplitude?
What is threshold frequency (fT)? What does threshold frequency depend on?
The minimum frequency of light that causes ejection of electrons is known as the threshold frequency fT. Threshold frequency depends on the type of metal being exposed to the radiation.
Why is the photoelectric effect, for all intense and purposes, an all or nothing response?
If the frequency of the incident photon is less than the threshold frequency, then no electron will be ejected because the photons do not have the sufficient energy to dislodge the electron from its atom.
If the frequency of the incident photon is greater than the threshold frequency, then an electron will be ejected, and the maximum kinetic energy of the ejected electron will be equal to the difference between hf and hfT (the work function).
What is the work function?
W=hfT
In solid-state physics, the work function is the minimum thermodynamic work needed to remove an electron from a solid to a point in the vacuum immediately outside the solid surface (hfT).
The work function can be thought of as activation energy. It must be matched or exceeded to cause the reaction (escape of an electron) to occur.
What will happen if the frequency of incident light is less than the threshold frequency?
What will happen if the frequency of incident light is more than the threshold frequency?
What will happen if the incident light beams frequency is above the threshold frequency and is of a high intensity?
An electron will be ejected.
An electron will not be ejected.
More current will be produced, the net charge flow per unit time.
How do you calculate the maximum kinetic energy of an ejected electron?
If the frequency of the incident photon is greater than the threshold frequency, then an electron will be ejected, and the maximum kinetic energy of the ejected electron will be equal to the difference between hf and hfT (the energy of the electron and the work function).
How do we calculate the energy of a photon?
How do we calculate wavelength with the given frequency of light given the energy of a photon?
In terms of energy and wavelength, what does it mean for waves with higher frequency? For waves with lower frequency?
Higher frequency waves have shorter wavelength and higher energy.
Lower frequency waves have longer wavelength and lower energy.
How do we calculate the maximum kinetic energy of an ejected electron? What are the conditions by which an electron will be ejected?
The conditions by which an electron will be ejected are that the electron has more energy than the work function (the energy required to eject and electron, hfT)
Example photoelectric effect page 332
MCAT concept check photoelectric effect 9.1 page 332 question 1
How does the work function relate to the energy necessary to emit an electron from a metal?
The energy of the photon must be greater than the work function in order for an electron to be emitted from the metal.
From the book: the work function describes the minimum amount of energy necessary to emit an electron. Any additional energy from a photo will be converted to excess kinetic energy during the photoelectric effect.
In the photoelectric effect, does higher intensity light eject more electrons or higher kinetic energy electrons?
In the photoelectric effect, a higher intensity of light results in more electrons being ejected, not higher kinetic energy of the individual electrons; the kinetic energy of the electrons is determined by the frequency of the light, not its intensity.
More light intensity increases the amount of electrons emitted, observed as increased current.
MCAT concept check photoelectric effect 9.1 page 332 question 2
What does the threshold frequency depend upon?
The threshold frequency depends on the type of metal being exposed to the radiation.
The threshold frequency depends on the chemical composition of a material, that is the identity of the metal.
MCAT concept check photoelectric effect 9.1 page 332 question 3
What electrical phenomenon results from the application of the photoelectric effect?
The accumulation of moving electrons creates a current during the photoelectric effect.
As long as the frequency of light is greater than the threshold frequency ( which also means the energy of the photon is greater than the work function) electrons will be emitted and a current is created.
Higher energy electrons manifest a higher kinetic energy, higher intensity light emits more electrons and increases the current observed.
What does the Bohr model state?
The Bohr model states that electron energy levels are stable and discrete, corresponding to specific orbits.
An electron can jump from a lower energy to a higher energy orbit by absorbing a photon of light of precisely the right frequency to match the energy difference between the orbits (E=hf).
If a photon does not carry enough energy, then the electron cannot jump to a higher energy level.
When an electron falls from a higher energy level to a lower energy level, a photon of light is emitted with an energy equal to the energy difference between the two orbits.
MCAT concept check absorption and emission of light 9.2 page 336 question 1
What determines the absorption spectrum of a single atom?
The energy differences between ground state electrons and higher level electron orbits determine the frequencies of light a particular material absorbs (its absorption spectrum).
MCAT concept check absorption and emission of light 9.2 page 336 question 2
True or false: small changes in chemical structure only minimally impact light absorption and emission patterns.
False. Small changes, such as protonation and deprotonation, change in oxidation state or bond order, and other differences may cause dramatic changes in light absorption in a material.
MCAT concept check absorption and emission of light 9.2 page 336 question 3
During which electronic transitions is photon emission most common?
When electrons transition from a higher energy state to a lower energy state, they will experience photon emission.
MCAT concept check absorption and emission of light 9.2 page 336 question 4
What causes fluorescence?
Fluorescence is a special step wise photon emission in which an electron returns to the ground state through one or more intermediate excited states.
Each energy transition releases a photon of light. With smaller energy transitions than the initial energy absorbed, these materials can release photons of light in the visible range.