Chapter 9 Flashcards

1
Q

Covalent vs ionic bonds vs metallic bonding?

A

Ionic- metal and nonmetal transfer electrons
Covalent- non metal and non metal sharing electrons
Metallic- metal and metal where electrons are polled

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What does the amount of valence electrons have to do with an atoms stability?

A

Full octet=very stable

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

How do you draw the Lewis symbols for ionic bonds? KCl?

A

Take the metal and transfer the electrons to the non metal to make a full octext and add a negative charge to the non metal and a positive charge to the metal

K+[Cl]- (has full octet around Cl)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What bond is the strongest? Single, double or triple? Which one is the shortest?

A

Triple bond is the strongest and shortest

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What do δ+and δ- minus mean?

A

Partial positive and negative charge of atoms that show they are unequally shared in bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What is a polar bond?

A

Having a positive pole and a negative pole

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is the electronegativity of fluorine?

A

4.0 (the highest)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What does the electronegativity difference between bonded atoms have to do with the polarity of the bond?

A

The greater the electronegativity difference, the more polar the bond is

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What is a covalent bond and it’s electronegativity difference?

A

Non metal and non metal

Small (0.0-0.4)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is a polar covalent bond and what is it’s electronegativity difference?

A

An intermediate in nature between pure covalent and ionic bonds
Intermediate (0.4-2.0)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What is an ionic bond and what is it’s electronegativity difference?

A

Metal and non metal

Large (2.0-4.0)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

How do you pick the central atom in the Lewis diagrams?

A

The least electronegative element (francium would be the least electronegative)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

How do you draw resonance structures?

A

Put one structure with one bond then put a double header arrow and the same structure with the bond on the other element

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What is formal charge?

A

A fictitious charge assigned to each atom that shows the charge an atom would have shared equally between bonded atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What elements disobeys the octet rule and how?

A

Boron does because in some cases it can only have 6 valence electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is bond energy?

A

The energy required to break 1 mole of the bond in the gas phase
The stronger the bond, the more chemically stable and less chemically reactive

17
Q

What is endothermic in terms of bond formation?

A

Breaking bonds (positive bond energy)

When strong bonds break and weak bonds form

18
Q

What is exothermic in terms of bond formation?

A

Forming bonds (negative bond energy)

When weak bonds break and strong bonds form

19
Q

How to we find the change in enthalpy of a reaction using bond energies?

A

ΔΗrxn=Σ(bonds broken) + Σ(bonds formed)

Bonds broken is positive
Bonds formed is negative

20
Q

What does the electron sea model of metallic bonds have to do with them being good conductors of electricity?

A

The electrons are free to move in response to an electric potential and generate an electric current

21
Q

How to find smallest or largest dipole moment when given a list of compounds?

A

Smallest will have the two closest elements (least electronegativity difference)
Largest will have the two furthest elements (largest electronegativity difference)

22
Q

What does VSEPR stand for? What does it state?

A

Valence shell electron pair repulsion theory

States that electrons that make bonds try to get as far as possible from eachother

23
Q

What are the two groups of VSEPR?

A

Electron geometry- geometry of all electron groups around an atom
Molecular geometry- the geometry of bonding electrons groups only