Chapter 8: Chemical Reactions and Thermochemistry Flashcards
1
Q
types of reactions
A
- combination/synthesis
- decomposition
- single replacement/single displacement (AB+C–>AC+B)
- double replacement/ double displacement (precipitation, acid-base, reaction that gives off gaseous compound)
- combustion (CxHy + O2 —> CO2 + H2O)
- redox
2
Q
heat of formation
A
- number of kJ absorbed when the ONE mole of compound is formed (positive means heat absorbed and negative means heat given off)
- if ΔH is a large negative value, then difficult to decompose (put more energy in)
- standard heat (enthalpy) of formation is final minus initial of all elements not in their standard state (at 25 * C and 1 atm)
3
Q
activity series (generally)
A
- most reactive: alkali metals and alkaline earth metals
- 2nd most reactive: first row of transition metals, Al, Cd
- least reactive: Ag, Au, Pt
4
Q
solubility rules
A
-any compound with NH4+, nitrate, salt with group 1 elements, acetates, bicarbonates, chlorates are soluble
5
Q
hydrolysis reaction
A
-opposite of neutralization (acid/base) reactions: salt and water react to form acid and base
6
Q
entropy (ΔS)
A
-measure of disorder
7
Q
heat of combustion
A
-heat released by the combustion of one mol of a reactant
8
Q
First Law of Thermodynamics
A
- energy i neither created nor destroyed
- allows for the use of Hess’s Law
9
Q
standard enthalpy of a reaction
A
ΔHoreaction=∑nΔHof(products)−∑nΔHof(Reactants)