Chapter 11: Acids, Bases, and Salts Flashcards
properties of acids
- water (aqueous) solutions of acids conduct electricity
- acids willreact with metals that are more active than hydrogen ions
- litmus (when in contact with acid, purple becomes pink-red) and phenolphthalein (pink to colorless)
strong acids
HNO3, HCl, HBr, HI, HClO4, H2SO4
strong bases
LiOH, NaOH, KOH, RbOH, CsOH, Ca(OH)2, Sr(OH)2, Ba(OH)2
Arrhenius Acid/Base Theory
- acid is a substance that produces H+ ions in aq. soln.
- base is a substance that produces OH- ions in aq. soln.
properties of bases
- conduct electricity in aq. soln.
- litmus changes from red to blue, phenolphthalein turns pink from colorless
Bronstead-Lowry Acid Base Theory
-acids are proton donros and bases are proton acceptors
conjugate acid/base
- conjugate acid is the base after receiving the proton
- conjugate base is the acid after giving away a proton
- the stronger the acid, the weaker the conjugate base bc attracting a proton would cause the strong acid to just give off the proton again (HCl would become Cl- and then wouldn’t stay unionized as HCl)
Lewis Theory
-acid is the electron pair acceptor and base is the electron pair donor (when H+ bonds, it gains electron pair)
titration
- use of volumetric measurement to determine the concentrations of “unknown” solutions or solids
- slowly drip unknown solution into known concentration solution until reach end point (the indicator changes color)
equivalence point
- enough acid i added to neutralize the base (and vice versa)
- AKA moles of titrate equal moles of analate
useful equations
MaVa=MbVb for titrations
-keep in mind examples where acids and bases have more than one hydrogen or hydroxide when the equation is balanced (need 2HCl for every one Ca(OH)2)
molarity= mols/L
how to pick an indicator
- end point is neutral: BTB, litmus
- end point is acidic: methyl orange
- end point is basic: phenolphthalein
buffer
- create solutions in equilibrium that are able to resist changes in pH by bonding with the added H+ or OH-
- created by weak acids or weak bases and their conjugates
salt
-ionic compounds created in neutralization, single/double displacement, synthesis, or metallic oxide with nonmetallic oxide
amphoteric substance
-substances that can act as the proton donor or acceptor (H2O, NH3, HCO3-)