Chapter 6 (section 9) Flashcards

1
Q

What is the standard state for a gas?

A

Pure gas at a pressure of exactly 1 bar.

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2
Q

What is the standard state for a liquid or solid?

A

The pure substance in its most stable form at a pressure of 1 bar and at the temperature of interest (usually 298 k)

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3
Q

What is the standard state for a substance in solution?

A

A concentration of exactly 1 mol/L

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4
Q

What is the standard enthalpy change (ΔᵣHº)?

A

The change in enthalpy for a process when all reactants and products are in their standard states.

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5
Q

What does the º on the ∆ᵣHº indicate?

A

It indicates standard state. All the products and reactants are in their standard states

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6
Q

What is the standard enthalpy of formation ΔfHº for a pure compound?

A

The chnage in enthalpy when 1 mol of the compound forms from its ocnstituent elements in their standard states

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7
Q

What is the standard enthalpy of formation ΔfHº for a pure element in its standard state?

A

0 kJ/mol

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8
Q

Define standard heat of formation

A

The change in enthalpy when 1 mol of a compound forms from its constituent elements in their standard states.

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9
Q

standard enthalpy of formation is also called …?

A

standard heat of formation

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10
Q

The _____ of standard enthalpy of formation corresponds to the decomposition of a compound into its elements in their standard states.

A

negative

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11
Q

ΔᵣHº = ∑ np ∆fHº (products) - ∑ nr ∆fHº (recatants)

What is this equation in words?

A

To calculate ΔᵣHº, subtract the enthalpies of formation of the reactants multiplied by their stoichiometric coefficients from the enthalpies of formation of the products multiplied by their stoichimetric coeffecients

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