Chapter 6 (section 6) Flashcards

1
Q

the enthalpy of a system is …?

A

the sum of its internal energy and the product of its pressure and volume

H = U + PV

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2
Q

What is the equation for the change of the enthalpy of a system?

A

ΔH = ΔU + PΔV

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3
Q

Define exothermic reaction

A

a chemical reaction that releases heat into its surroundings; for an exothermic reaction, ∆H < 0

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4
Q

A positive ΔH indicates …?

A

heat flows into the system as the reaction occurs

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5
Q

A negative ΔH indicates …?

A

heats flows out of the system as a reaction occurs

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6
Q

A positive ΔH means the reaction is _____

A

endothermic

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7
Q

A negative ΔH means the reaction is ___

A

exothermic

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8
Q

Define endothermic reaction

A

a chemical reaction that absobrbs heat from its suroroundings; for an endothermic reaction, ∆H > 0

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9
Q

What is symbol the enthalpy change of a reaction?

A

ΔᵣH

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10
Q

The enthaply change of reaction is also called _____ __ ____ or ____ ____

A

enthalpy of reaction

heat of reaction

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11
Q

Define heat of reaction

A

the enthalpy change for a chemical reaction

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12
Q

Define entahlpy of reaction

A

the enthalpy change for a chemical reaction

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13
Q

The enthalpy of the reaction is a ____ property. This means it depends on…?

A

extensive

the amount of material undergoing the reaction.

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14
Q

Define enthalpy (H)

A

The sum of the internal energy of a system and the product of its pressure and volume; the energy associated with the breaking and forming of bonds in a chemical equation

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15
Q

Since internal energy, pressure, and volume are all state functions, enthaply is….?

A

also a state function

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16
Q

If pressure is constant, what is the change in enthalpy equal to?

A

Temperature

17
Q

The value of ∆ᵣH for a chemical reaction is….?

A

the amount of heat absorbed or evolved in the reaction under conditions of constant pressure

18
Q

Where does energy come from in an exothermic reaction seeing as both the temperature of the system and the surroundings rises?

A

The energy comes from bonds breaking and the forming in a way which lowers the potential energy of the system.

19
Q

Where does the energy go in an endothermic reaction seeing as both the temperature of the system and the surroundings drops?

A

The energy goes into breaking bonds and then forming bonds of higher potential energy increasing the potential energy of the system.