Chapter 5 - Electrons in Atoms Flashcards

0
Q

quantum

A

the amount of energy required to move an electron from one energy level to another energy level

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1
Q

energy levels

A

the fixed energies an electron can have

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2
Q

quantum mechanical model

A

the modern description of the electrons in atoms that comes from the mathematical solutions to the Schrodinger equation

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3
Q

atomic orbital

A

a region of space in which there is a high probability of finding an electron

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4
Q

electron configurations

A

the ways in which electrons are arranged in various orbitals around the nuclei of atoms

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5
Q

aufbau principle

A

electrons occupy the orbitals of lowest energy first

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6
Q

Pauli exclusion principle

A

atomic orbital may describe at most two electrons

to occupy the same orbital, they must have opposite spins

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7
Q

Hund’s rule

A

electrons occupy the orbitals of the same energy in a way that makes the number of electrons with the same spin direction as large as possible

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8
Q

amplitude

A

the wave’s height from zero to crest

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9
Q

wavelength

A

the distance between the crests

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10
Q

symbol for wavelength

A

lambda

upside down y

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11
Q

frequency

A

the number of wave cycles to pass a given point per unit of time

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12
Q

symbol for frequency

A

v

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13
Q

unit for frequency

A

s^-1 or hertz

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14
Q

electromagnetic radiation

A

radio waves, microwaves, infrared, visible light, ultra violet, X-rays, gamma rays

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15
Q

spectrum

A

wavelengths of visible light that are separated when sunlight passes through a prism

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16
Q

atomic emission spectrum

A

the frequencies of light emitted by an element that separate into discrete lines

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17
Q

ground state

A

an electron has its lowest possible energy

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18
Q

photons

A

light quanta

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19
Q

Heisenberg uncertainty principle

A

it is impossible to know exactly both the velocity and the position of a particle at the same time

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20
Q

what did Democritus say about the atom

A

indivisible and indestructible

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21
Q

Dalton

A

solid sphere:
all elements composed of tiny indivisible particles
atoms are unique to that element
atoms of different elements can physically mix or chemically combine in simple whole number ratios to form compounds
chemical reactions occur when atoms are separated, joined, or rearranged, but they will not change elements

22
Q

Thomson

A

plum pudding model - electrons

23
Q

Rutherford

A

nucleus

positive dense center with electrons buzzing around

24
Q

Bohr

A

electrons go in circular orbits

25
Q

Schrodinger

A

quantum mechanical model - electron cloud

26
Q

How many sublevels are in n=1

A

1

27
Q

What type of orbitals are possible in n=1

A

s

28
Q

max # of electrons in s

A

2

29
Q

max. number of electrons in n=1

A

2

30
Q

how many sublevels in n=2

A

2

31
Q

type of orbitals in n=2

A

s

p

32
Q

max number of electrons in p

A

6

33
Q

max number of electrons in n=2

A

8

34
Q

number of sublevels in n=3

A

3

35
Q

types of orbitals in n=3

A

s
p
d

36
Q

max number of electrons in d

A

10

37
Q

max number of electrons in n=3

A

18

38
Q

number of sublevels in n=4

A

4

39
Q

orbitals in n=4

A

s
p
d
f

40
Q

max number of electrons in f

A

14

41
Q

max number of electrons in n=4

A

32

42
Q

atomic orbitals in order

A
1s
2s
2p
3s
3p
4s
3d
4p
5s
4d
5p
6s
4f
5d
6p
7s
5f
6d
7p
43
Q

3d^1 name the parts

A

3 - energy level/principal energy level
d - orbital/sublevel
1 - number of electrons

44
Q

what happens when an atom absorbs energy

A

it goes from the stable ground state to the unstable excited state

45
Q

what happens when an electron moves to a lower energy level

A

energy is released as light

46
Q

What could Rutherford’s model not do?

A

explain the chemical properties of elements

47
Q

what does the quantum mechanical model propose

A

electrons move only in specific circular paths, or orbits, around the nucleus

48
Q

what does each sublevel of a principal energy level correspond to?

A

an orbital shape describing where the electron is likely to be found

49
Q

what tell you how to find the electron configurations of atoms

A

aufbau principle
Pauli exclusion principle
Hund’s rule

50
Q

why do some electron configurations differ from those assigned using the aufbau principle?

A

excited unstable ones that are not all filled

51
Q

how are wavelength and frequency of light related

A

they are inversely proportional

52
Q

the light emitted by an electron moving from a higher level to a lower level has a frequency ______ to the energy change of the electron

A

directly proportional

53
Q

the difference between classical mechanics and quantum mechanics

A

classical mechanics adequately describes the motions of bodies much larger than atoms
quantum mechanics describes the motions of subatomic particles and atoms as waves