Chapter 4 Flashcards
matter is found in 3 states
Gas, Liquid, Solid
a hazardous material’s state of matter determines…
how mobile the material will become
compressible substance, with no specific volume, that tends to assume the shape of a container. molecules move about most rapidly in this state
Gas
incompressible substance with a constant volume that assumes the shape of its container; molecules flow freely, but substantial cohesion prevents them from expanding as a gas would
liquid
substance that has a definite shape and size; the molecules of a solid generally have very little mobility.
solid
ERG isolation distance of a solid
75 ft
ERG isolation distance of a liquid
150 ft
ERG isolation distance of a gas
330 ft
solid particle that is formed or generated from solid organic or inorganic materials by reducing its size through mechanical processes, such as crushing, grinding, drilling, abrading, or blasting.
dust
suspension of particles that form when material from a volatilized solid condenses in cool air.
fume
finely divided liquid suspended in the atmosphere
mist
form of pressurized mist characterized by highly respirable, minute liquid or solid particles.
aerosol
solid particle whose length is several times greater than its diameter is formed by a disruption of the natural state.
fiber
gaseous form of a material that is normally in a solid or liquid state at room temperature and pressure.
vapor
visible aerosol of a liquid formed by condensation.
fog
incidents involving gases are potentially the most _____________ for emergency responders
dangerous
gas that, at normal temperature, exists solely as a gas when pressurized in a container
compressed gas
confined gas that at normal temperatures exists in both liquid and gaseous states
liquified gas
gases may have pressures as high as _________ such as liquid helium
15000 psi
materials kept under pressure and/or temperatures higher or lower than ambient conditions may….
change state upon release
the ration that gas will expand
expansion ratio
unit of measure typically used to express particle size
micron
characteristics of a material that do not involve the chemistry or chemical nature of the material
physical properties
pressure exerted by a saturated vapor above its own liquid in a closed container.
vapor pressure
materials with a vapor pressure over _________ will be gases under normal conditions
760 mmHg
in vapor pressure, gases rise above the liquid and exerts a _____________ pressure
downward
__________ is the baseline measurement for pressure
atmospheric pressure
the lower the boiling point of a liquid the ________ its vapor pressure will be
higher
BLEVE
boiling liquid expanding vapor explosion
temperature at which a solid substance changes to a liquid state at normal atmospheric pressure
melting point
temp at which liquid becomes a solid
freezing point
changing directly from solid to gas without ever going into a liquid state
sublimate
weight of a given volume of pure vapor or gas compared to the weight of an equal volume of dry air at the same temperature and pressure
vapor density
percentage of a material (by weight) that will dissolve in water at ambient temperature
solubility
when a water soluble liquid combines with water, the two liquids mix.
polar solvent
two or more liquids’ capability to mix together
miscibility
incapable of being mixed or blended with another substance
immiscible
ratio of the density of a material to the density of a standard material, usually an equal volume of water, at standard conditions of pressure and temperature
specific gravity
a chemicals ability to remain in the environment
persistence
measure of the thickness or flowability of a liquid at a given temperature
viscosity
chemical nature of a material and the behaviors and interactions that occur at a molecular level
chemical properties
most hazardous materials incidents involve
flammable materials
minimum temp at which a liquid or volatile solid gives off sufficient vapors at its LEL to form an ignitable mixture with air near its surface
flash point
temp at which a liquid or volatile solid gives off enough vapors to support continuous burning
fire point
any liquid with a flashpoint below 100° F
flammable liquid
any liquid having a flash point at or above 100°F and below 200°F
combustible liquid
incapable of combustion under normal circumstances. normally used when referring to liquids or gases.
nonflammable