Chapter 4 Flashcards

0
Q

John Dalton

A
  • English Chemist
  • Developed an atomic theory which used scientific method
  • Elements are made of invisible particles called atoms (not invisible=not true)
  • Atoms of the same element are identical. Atoms from 1 element= dif from other element
  • Atoms from diff atoms form mixtures/ compounds
  • Chem. reactions arrange atoms in dif combos, but atoms can’t change from one atom to another.
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1
Q

Democritus’ Atomic Theory

A
  • Greek Philosopher
  • Suggested the existence of atoms
  • Believed atoms were indivisible and indestructible
  • Theory flawed cuz: didn’t explain chem. behavior
    - Not based scientific method
    - Not supported by experiment data
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2
Q

How did John Dalton observe atoms?

A
  • Observed when atoms mix, they maintain their own identity unless they combine in a chem. reaction
  • Studied ration of these combinations
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3
Q

Evidence from Daltons experiments

A

-Every drop of mercury has the same chemical properties

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4
Q

J.J. Thomson

A
  • Stated electrons are negatively charged particles
  • Proved by filling with gas and put electrodes at each end connected to source of electricity
  • Neg electrode: cathode
  • Positive electrode: anode
  • When electricity passed through tube, stream of light appears (cathode ray)
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5
Q

Explanation of J.J. Thomson’s experiment

A
  • Anode attracts cathode ray
  • Cathode repels the cathode ray
  • Cathode ray=stream of tiny neg charged particles (fast moving)
  • Names particles corpuscles (electrons)
  • type of gas in tube does not effect electrons
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6
Q

Robert A Millikan

A
  • Carried out experiment to measure an electrons charge
  • Oil-droplet experiment: suspended neg charged oil droplets between two charged plates
  • Changed the voltage on the plates to see how this affected the droplet’s fall
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7
Q

Robert A Millikan charge of electron

A

-Found the charge of each oil droplet to be a multiple of 1.6 x 10^-19 coulomb ( the charge of an electron)

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8
Q

Eugen Goldstein

A
  • Observed the cathode ray tube: found rays traveling in the opposite direction of the cathode rays
  • concluded rays were subatomic positive particles (protons)
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9
Q

James Chadwick

A

-Confirmed the existence of the neutrons

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10
Q

Plum Pudding Model

A

-JJ Thomson thought electrons were evenly distributed throughout a postitively charged atoms

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11
Q

Plum pudding model vs. Atomic Model

A
  • PP no nucleus
  • PP spread through out the atom
  • PP Protons have no definite shape and appear as dough in a ball of cookie dough
  • PP no neutrons
  • PP no empty space
  • PP no motion
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12
Q

Rutherford’s Gold Foil experiment

A
  • Shot alpha beams (Helium atom wo/ electrons) through gold foil
  • If plum pudding model was correct, beams would pass through (atoms are soft)
  • What happened: most passed through, some went in diff direction
  • Concluded: Existence of Nucleus, nucleus is dense w/ positive charge, most of atom is empty space
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13
Q

Rutherford’s atomic model

A
  • Protons and neutrons located in positive charged center(nucleus)
  • electron orbits the nucleus
  • Nucleus as small as marble in football stadium
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14
Q

Atomic number

A
  • Number of protons in element
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15
Q

Mass Number

A
  • The number of protons and neutrons in an element
16
Q

How do you find the number of neutrons in an elements

A
  • (Mass number - Atomic Number)= number of neutrons
17
Q

What are the two ways to show an elements mass number?

A
  • Shorthand: atomic number is subscript, mass number super script, left of element
  • Element with dash then mass number ( gold-197 or Au-197)
18
Q

Isotopes

A
  • Atoms that have the same number of protons but different number of neutrons
  • Diff number of neutrons= different mass number
  • Isotopes of carbon (black gunk and diamond)
19
Q

What is used to find the mass of an atom?

A
  • spectrometer

- Even the largest atoms are incredibly small

20
Q

Atomic Mass Unit

A
  • Defined as one-twelfth of the mass of a carbon-12 atom

- Neutrons and protons= 1 amu

21
Q

arithmetic mean

A
  • the average of 2 or more pieces of data
22
Q

Atomic mass

A
  • a weighted average mass of the atoms in a naturally occurring sample of the element
  • Below element symbol on a periodic table
23
Q

Nucleus and Electron Mass and volume

A
  • Nucleus takes up small volume, 99% of mass

- Electrons take up a lot of volume, very little mass

24
Q

Two ways to represent charge

A
  • Whole numbers (1 electron, 2, 3…)

- (number of electrons) x 1.6 x10^-19 columbs