Chapter 3 - Chemical Bonding Flashcards
Ionic bonds
Electrostatic forces of attraction between oppositely charged ions
Structure of ionic compounds
Giant crystal lattice
- formed from the 3-dimensional regular packing of positive and negative ions
- bonded by strong electrostatic forces of attraction
- Ionic compounds have high melting and boiling points
- A large amount of heat energy is required to overcome the strong forces of attraction between the oppositely-charged ions
- Ionic compounds are soluble in water but insoluble in organic solvents
- Water molecules are polar molecules → form electrostatic forces with the ions, causing ions to separate and dissolving the compound
- Organic solvents are non-polar molecules which cannot attract the ions and are hence unable to dissolve the compound.
Organic solvents (examples)
- hexane
- ethanol
- turpentine
- petrol
- Ionic compounds do not conduct electricity in solid but conduct electricity in molten or aqueous state
- Solid state → ions are fixed within the crystal lattice and only vibrate about the lattice points
- Molten/Aqueous state → ions are free to move (mobile) and can act as charge carriers to conduct electricity
- Ionic compounds are brittle and shatter when hit
- When the lattice is hit, a layer of ions is shifted so that ions with the same charges are lined up together
- These like charges repel each other and split the ionic lattice
Covalent bonds
Electrostatic forces of attraction between the positive nuclei of the 2 atoms and the bonding electrons shared between them
Chemical formula of methane
CH4
Chemical formula of hydrogen peroxide
H2O2
Structure of simple molecules (covalent)
- Simple discrete molecules at lattice points
- Atoms of the molecules are held by strong covalent bonds
- Weak intermolecular forces (van der waals forces/hydrogen bonds) between the molecules
Hydrogen bonds
- H directly bonded to N (nitrogen), O (oxygen) or F (fluorine)
- Stronger than van der waals forces
Structure of macromolecules (covalent)
- Atoms at lattice points that can be extended infinitely in 3 dimensions to form a giant lattice
Allotrope
Solid forms of an element with different molecular structures
Diamond (structure)
- Each C atom forms 4 single covalent bonds with 4 other C atoms
- Tetrahedral arrangement
Graphite (structure)
- Each C atom forms 3 single covalent bonds with 3 other C atoms
- The 4th unpaired valence electron of each C atom is delocalised along the layers
- Layers are held by weak van der waals forces
- Hexagonal arrangement (flat, parallel layers)
- Simple molecules have low melting and boiling points
- A small amount of heat energy is required to overcome the weak intermolecular forces of attraction between molecules
- Simple molecules are generally soluble in organic solvents and insoluble in water
- Exceptions: HCl (hydrogen chloride) exist as simple discrete molecules in organic solvents but ionises in water to form H+ and Cl-
- Simple molecules do not conduct electricity in any state
- There are no mobile charged particles (delocalised electrons/mobile ions) to carry charges
- Exceptions: HCl (hydrogen chloride) ionises in water to form acidic solutions with mobile H+ and Cl- ions which conduct electricity
- Simple molecules are generally soft
- A small amount of energy is required to break and deform the weak intermolecular forces between molecules
- Macromolecules have high melting and boiling points
- A large amount of heat energy is required to overcome the strong covalent bonds between atoms in the molecules
- Macromolecules are insoluble in all solvents
- A large amount of energy is required to overcome the strong covalent bonds between atoms
- Macromolecules do not conduct electricity in any state
- Substances made up of neutral atoms and do not contain mobile charge particles (delocalised electrons/mobile ions) to carry charges
- Exceptions: Graphite is a good conductor of electricity due to the presence of delocalised electrons along the layers to conduct electrcity
- Macromolecules are generally hard
- A large amount of energy is required to break and deform the strong covalent bonds between the atoms
- Exceptions: Graphite is soft as layers are held by weak van der waals forces
Metallic bonds
Strong electrostatic attraction between positive metal ions and negative delocalised ions (mobile valence electrons of the metal)
Structure of metallic compounds
Giant metallic structure
- a lattice of bonded positive metal ions
- surrounded by a ‘sea of mobile electrons’
What are factors affecting the strength of metallic bonds?
- Number of valence electrons
2. Size of metal ions
1) Number of valence electrons
- As the number of valence electrons increases, the charge of the positive metal ion increases
- The number of delocalised electrons increases which then increases the strength of the metallic bond
2) Size of metal ions
- The smaller the metal ions, the closer the positive nuclei to the delocalised electrons
- This results in a greater electrostatic attraction between the positive nuclei and the delocalised electrons → stronger metallic bonds
- Metals have high melting and boiling points
- A large amount of energy is required to overcome the strong electrostatic forces of attraction between positive metal ions and the negative delocalised electrons
- Metals are generally insoluble in water and organic solvents
- Exceptions: Reactive metals such as sodium and potassium can react with water to give hydrogen gas
- Metals are good conductors of electricity
- In the solid and molten states, delocalised electrons rapidly carry charges through the metal lattice
Electrical conductivity increases with greater number of ________
valence electrons
- Metals are good conductors of heat
- When a metal is heated, delocalised electrons gain kinetic energy and moves faster to transfer the gained energy throughout the metal
- Heat travels through the metal lattice as a result of rapid movement of delocalised electrons
Define “malleable”
Can be hammered into different shapes without breaking
Define “ductile”
Can be drawn into wires without breaking
- Metals are malleable and ductile
- Layers of atoms can slide over one another without breaking the strong metallic bonds