Chapter 2 - Qualitative Analysis Flashcards
Test for gases
- Observe the colour of the gas
- Conduct a litmus test (both blue and red)
3a. Perform an acidified potassium permanganate(VII) test
3b. Perform a splint test - Perform a limewater test
Hydrogen, H2
Colourless, odourless.
Light splint is extinguished with a ‘pop’ sound.
(No change observed for litmus test.)
Oxygen, O2
Colourless, odourless.
Glowing splint is rekindled/relit.
(No change observed for litmus test.)
Carbon dioxide, CO2
Colourless, odourless. White ppt (calcium carbonate) is produced when gas is bubbled into limewater (calcium hydroxide). Moist blue litmus turns red.
Chlorine, Cl
Greenish-yellow, pungent.
Moist blue litmus turns red, and is then bleached white.
Sulfur dioxide, SO2
Colourless, pungent.
Acidified potassium manganate(VII), KMnO4, turns from purple to colourless (decolourised).
Moist blue litmus turns red.
Ammonia, NH3
Colourless, pungent.
White fumes of NH4Cl are observed when a glass rod dipped in concentrated hydrochloric acid is brought near the gas.
Moist red litmus turns blue.
Water vapour, H2O
Colourless, odourless. Anhydrous cobalt(II) chloride, CoCl2, paper turns from blue to pink.
Hydrogen chloride, HCl
Colourless, pungent.
White fumes of NH4Cl are observed when a glass rod dipped in aqueous ammonia is brought near the gas.
Moist blue litmus turns red.
Test for water
Add a few drops of the sample to anhydrous copper(II) sulfate. Anhydrous CuSO4 changes from white to blue.
Zn2+ in sodium hydroxide
White precipitate soluble in excess sodium hydroxide to give colourless solution
Zn2+ in aqueous ammonia
White precipitate soluble in excess aqueous ammonia to give colourless solution
Al3+ in sodium hydroxide
White precipitate soluble in excess sodium hydroxide to give colourless solution
Al3+ in aqueous ammonia
White precipitate insoluble in excess aqueous ammonia
Pb2+ in sodium hydroxide
White precipitate soluble in excess sodium hydroxide to give colourless solution
Pb2+ in aqueous ammonia
White precipitate insoluble in excess aqueous ammonia
Ca2+ in sodium hydroxide
White precipitate insoluble in excess sodium hydroxide
Ca2+ in aqueous ammonia
No precipitate (in aqueous ammonia)
Cu2+ in sodium hydroxide
Blue precipitate insoluble in excess sodium hydroxide
Cu2+ in aqueous ammonia
Blue precipitate soluble in excess aqueous ammonia to give dark blue solution
Fe2+ in sodium hydroxide
Green precipitate insoluble in excess sodium hydroxide
Fe2+ in aqueous ammonia
Green precipitate insoluble in excess aqueous ammonia
Fe3+ in sodium hydroxide
Reddish-brown precipitate insoluble in excess sodium hydroxide
Fe3+ in aqueous ammonia
Reddish-brown precipitate insoluble in excess aqueous ammonia
NH4+ in sodium hydroxide
No precipitate observed (in sodium hydroxide)
NH4+ in aqueous ammonia
A colourless, pungent gas evolved, which turns moist red litmus blue. Gas is ammonia.
How to differentiate white ppt of Pb2+ and Al3+?
Add potassium iodide (KI):
- no precipitate → Al3+
- yellow precipitate (PbI2) → Pb2+
Na+ flame test
Dark yellow
Ba2+ flame test
Pale green
Ca2+ flame test
Red
K+ flame test
Lilac
Pb2+ flame test
Greyish white
Cu2+ flame test
Bluish green