Chapter 2: Acids and Bases Flashcards

1
Q

A species that loses a proton.

A

Bronsted Acid

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2
Q

A species that gains a proton.

A

Bronsted Base

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3
Q

Positively charged hydrogen ion.

A

Proton

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4
Q

Any species that has a hydrogen can potentially act as a(n) _____

A

Acid

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5
Q

Any species that has a lone pair can potentially act as a(n) _____

A

Base

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6
Q

A reaction in which an acid donates a proton to a base or accepts a share in a base’s electrons.

A

Acid-base Reaction

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7
Q

A species loses a proton to form this.

A

Conjugate Bass

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8
Q

A species accepts a proton to form this

A

Conjugate Acid

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9
Q

A ______ base has a high affinity for a proton

A

Strong

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10
Q

A measure of the tendency of a compound to lose a proton

A

Acidity

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11
Q

A measure of a compound’s affinity for a proton.

A

Basicity

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12
Q

A _____ base has a low affinity for a proton.

A

Weak

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13
Q

The stronger the acid, the _____ its conjugate base.

A

Weaker

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14
Q

A measure of the degree to which an acid dissociates in solution.

A

Acid Dissociation Constant

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15
Q

The _____ the acid, the more readily it loses a proton.

A

Stronger

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16
Q

Describes the tendency of a compound to lose a proton.

A

pKa

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17
Q

The _____ the acid, the smaller its pKa value.

A

Stronger

18
Q

Acids with a pKa of < 1 are considered

A

Very strong

19
Q

Acids with a pKa between 1-3 are considered

A

Moderately strong

20
Q

Acids with a pKa between 3-5 are considered

A

Weak

21
Q

Acids with a pKa between 5-15 are considered

A

Very weak

22
Q

Acids with a pKa > 15 are considered

A

Extremely weak

23
Q

Scale used to describe the acidity of a solution.

A

pH

24
Q

Compounds that have a COOH group.

A

Carboxylic acids

25
Q

Compounds that have an OH group.

A

Alcohols

26
Q

Compounds that result from replacing one or more of the hydrogens bonded to ammonia with a carbon-containing substituent

A

Amines

27
Q

The more _____ the base, the stronger its conjugate acid.

A

Stable

28
Q

_____ bases are weak bases.

A

Stable

29
Q

Two factors that affect the stability of a base are its _____ and its _____

A

Electronegativity and size

30
Q

Electronegativity _____ from left to right across the periodic table

A

Increases

31
Q

An sp carbon is _____ than an sp2 carbon, which is [same as first blank] than an sp3 carbon.

A

More electronegative

32
Q

_____ overrides electronegativity when determining relative acidities.

A

Size

33
Q

Inductive electron withdrawal _____ the strength of an acid.

A

Increases

34
Q

The term for replacing an atom in a compound.

A

Substitution

35
Q

Withdrawal of electrons through a sigma bond.

A

Inductive Electron Withdrawal

36
Q

A structure with localized electrons that approximates the true structure of a compound with delocalized electrons.

A

Resonance Contributor

37
Q

The actual structure of a compound with delocalized electrons; it is represented by two or more structures with localized electrons.

A

Resonance Hybrid

38
Q

_____ electrons are shared by more than two atoms.

A

Delocalized

39
Q

As the atom attached to the hydrogen increases in size, the strength of the acid _____.

A

Increases

40
Q

As the atom attached to the hydrogen increases in electronegativity, the strength of the acid _____

A

Increases

41
Q

A solution of a weak acid and its conjugate base.

A

Buffer Solution