Chapter 14 Temperature Flashcards
How does heat move from hot and cold objected
If object hotter than another, there is a net transfer of THERMAL energy from hot to cold until THERMAL equilibrium is reached
Thermal equilibrium is when there is no longer any net flow of thermal energy between them, thus SAME TEMPERATURE
Again what is thermal equilibrium
Thermal equkibkrum is when two objects have no net flow of thermal energy between them and thus at SAME TEMPERTAURE
What is zeroth law of thermodynamics?
If two objects are in thermal equilibrium with another, then all are actually in thermal equilibrium with each other
- could be useful
Why is it that thermometers can never hundred percent accurately measure temperature then
However why is it that measuring a human is correct
Because to measure temperature you want it to be the same temperature as the thing your measuring, however this won’t happen, as energy transfer will take place lowering the temperature if the surrounding that you wanted to measure in the first place!
2) negative feedback system whatever, energy always pumped out to ensure we correct tempertaure at all times so even if energy is taken it’s fine
Why do we touch things and think it’s cold? EVEN THO ITS SAME TEMP AS EVERYHTING ELSE
Heat transfer happens between hand and thing , and the more cold it is the greater rate if energy transfer and so especially for good conductors it feels even colder to touch EVEN THO ITS SAME TEMPERTAURE IS EVERYTHING ELSE AS IN THERMAL EQUILIBIRUM, but because rate of energy transfer is great feel fllld
What is the Kelvin scale formed on
Two points, absolute zero and triple point of water (where all three states at certain temp pressure aare in eaukibkrum )
But increments are the same as Celsius (so 1 increment)
Thus 273 increments from absolute 0 and triple point of water
Kinetic models of each state (3)?
Solid
- particles arranged in regular and arranged 3d structure
- string forces of attraction between the particles
- vibrate in fixed positions
Liquid
- particles free to move and take up shape of any container
- still forces of attraction
-
Gas
- negligible forces attraction between
Random motion
what is basic kinetic model that we try to prove using brownian motion
all matter made from particles
which have KE
what is Brownian Motion?
what is the velocities?
what is it a proof for and why?
1) its the random/ haphazard movement of particles suspended in a fluid (liquid/ gas) caused by collisons with surrounding fluid molecules.
2) this gives random velocities
3) Brownian Motion is a proof for the kinetic MODEL of matter, as it shows matter is made of particles, and that they have KE
how to observe brownian motion in the lab?
- use a smoke cell
-rthe smoke will scatter light and show against a dark background] - ## the jittery movements of the specks oflight are the smoke particles moving in random directions and random velocities due to colliding with ‘invisible’ water molecules
Density of things
Normally solid more dense except for water, thisnbevause hydorgen bonds hold them in fixed positions in an open lattice meaning average further apart than when liquid so less dense for same mass
What is INTERNAL ENERGY
Sum of randomly distributed kinetic and potential energies of atoms or molecules in a substance
What are examples of potential and kinetic
Kinetic jus kinetic energy, frim rotational or translational movement
But potential is due to electrostatic forces of attraction in intermolecular bonds
And the sum of this is internal energy
So explain graph of heating ice to a gas using internal energy ideas
TEMPERTAURE is just a measure of KINETIC energy. Thus heating will increase kinetic energy initially and thus internal energy.
However once they changing state, energy no longer increases TEMPERTAURE, however internal energy still increases!
- here energy is not kinetic so temp doesn’t increase. Here energy is transferred to POTENTIAL ENEEGY, so internal increase,
Only once phase changes will energy be transferred to kinetic again and temp revise
What are different potentials of different states. If you hear, are you inc or decreasinf the potential energy
How is a way to think about if something has high or low potential energy
Think of potential energy as jus energy transferred from surroundings to its form, so hotter = higher potential energy too and gases have highest potential at 0J, whereas solids have lowest potential
Or like potential is potential to make bonds. Solids have string bonds already so no pot Eileen
Potential is the ability to lose energy, we put a lot in gas, so it has most ability tomlose
Similar to chem, what happens when bonds re broken and what when bonds made
Bond breaking require energy bond making releases it, thus when water condensed it releases energy as bonds are made and in general potential energy decreases