Chapter 13: Unsaturated Conjugated Systems Flashcards
1
Q
A Diels-Alder reaction includes…
A
a dienophile and a 1,3-diene
2
Q
What reagents are used for radical allylic substitution?
2 alternatives
A
X2, ROOR: heat/light
or
NBS if Br, ROOR: heat/light
3
Q
What is the kinetic product of a strong acid reacting with a diene?
A
1,2-addition product
4
Q
What is the thermodynamic product of a strong acid reacting with diene?
A
1,4-addition product
5
Q
The kinetic product is…
A
less stable (faster rate)
6
Q
The thermodynamic product is…
A
more stable (slower rate)
7
Q
Which reaction is favored at higher temperature?
kinetic or thermodynamic
A
Thermodynamic (1,4)
