Chapter 11 Flashcards

1
Q

A solid, liquid, or gas used to start and sustain an intentionally set fire

A

Accelerant

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2
Q

A combustion in which Q (heat evolved) is used only to heat the reaction products. It is the basis of some simple combustion models

A

Adiabatic combustion

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3
Q

A flame in which the hot gas products and heated air drift up and away from the reaction zone due to density differences generated by heating

A

Buoyant flame

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4
Q

Another term for thermal distillation; applied to refining crude oil. Also incorporates degradation, or catalytic splitting of large molecules into smaller ones

A

Cracking

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5
Q

Burning or combustion that propagates at less than the speed of sound

A

Deflagration

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6
Q

Explosive combustion driven by pressure and a compressive shockwave

A

Detonation

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7
Q

The ratio of a fuel to air relative to a combustion reaction; typically expressed as a weight or volume percent comparison

A

Fuel/air ratio (F/A)

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8
Q

In arson fires, the device used to supply ignition energy

A

Incendiary device

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9
Q

A flame with defined regions delineated by temperatures and flame color

A

Laminar flame

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10
Q

A combustive mixture in which the concentration of oxidant is greater than the stoichiometric ratio

A

Lean mixture

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11
Q

The lowest mixture ratio of fuel and oxidant that will ignite and sustain combustion

A

Lower flammability limit (LFL)

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12
Q

The process of a solute moving in and out of a stationary phase

A

Mass transfer

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13
Q

Samples of pristine background material that must be analyzed to facilitate interpretation of analysis

A

Matrix controls

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14
Q

A measure of the amount of oxygen in a molecule that undergoes combustion. A positive oxygen balance means that all the oxygen needed for complete combustion is available intramolecularly

A

Oxygen balance

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15
Q

A product that is or was at one time derived from crude oil by distillation techniques

A

Petroleum distillate

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16
Q

The location(s) where a fire began

A

Points of origin

17
Q

A powdered combustive fuel used in firearms; typically contains nitroglycerin and guncotton

A

Propellants

18
Q

A high temperature decomposition that occurs in a reducing environment; an inlet for instrumentation and also an element of combustion reactions. Often combined with gas chromatography in forensic applications

A

Pyrolysis (combustion reactions)

19
Q

A combustive mixture in which the concentration of fuel is greater than the stoichiometric ratio

A

Rich mixture

20
Q

An older name for KNO3, potassium nitrate

A

Saltpeter

21
Q

The point at which fuel and oxidant create a zero oxygen balance

A

Stoichiometric equivalence (STE)

22
Q

The highest mixture ratio of fuel and oxidant that will ignite and sustain combustion

A

Upper flammability limit (UFL)

23
Q

The loss of lighter components of hydrocarbon mixtures used as accelerants

A

Weathering