Chapter 11 Flashcards
A solid, liquid, or gas used to start and sustain an intentionally set fire
Accelerant
A combustion in which Q (heat evolved) is used only to heat the reaction products. It is the basis of some simple combustion models
Adiabatic combustion
A flame in which the hot gas products and heated air drift up and away from the reaction zone due to density differences generated by heating
Buoyant flame
Another term for thermal distillation; applied to refining crude oil. Also incorporates degradation, or catalytic splitting of large molecules into smaller ones
Cracking
Burning or combustion that propagates at less than the speed of sound
Deflagration
Explosive combustion driven by pressure and a compressive shockwave
Detonation
The ratio of a fuel to air relative to a combustion reaction; typically expressed as a weight or volume percent comparison
Fuel/air ratio (F/A)
In arson fires, the device used to supply ignition energy
Incendiary device
A flame with defined regions delineated by temperatures and flame color
Laminar flame
A combustive mixture in which the concentration of oxidant is greater than the stoichiometric ratio
Lean mixture
The lowest mixture ratio of fuel and oxidant that will ignite and sustain combustion
Lower flammability limit (LFL)
The process of a solute moving in and out of a stationary phase
Mass transfer
Samples of pristine background material that must be analyzed to facilitate interpretation of analysis
Matrix controls
A measure of the amount of oxygen in a molecule that undergoes combustion. A positive oxygen balance means that all the oxygen needed for complete combustion is available intramolecularly
Oxygen balance
A product that is or was at one time derived from crude oil by distillation techniques
Petroleum distillate