Chapter 10: Organic Chemistry Flashcards
Define homologous series:
a family of similar compounds with similar chemical properties due to the presence of the same functional group.
Define functional group:
a group of atoms bonded in a specific way that is responsible for that homologous series characteristics
Alkane general properties:
saturated hydrocarbons
CnH2n+2
generally unreactive
uses of alkanes:
fuels
solvents
lubricants
starting compounds
Reactions of alkanes:
-combustion and substitution reactions with halogens
Alkenes general properties:
unsaturated hydrocarbons
CnH2n
more reactive than alkanes
Reactions of Alkenes:
Addition reactions
halogenation: add group 7 elements
hydration: add water
hydrogenation: add hydrogen
Define positional isomers:
when the functional group of the molecules occupies different positions the carbon chains
Alcohols general properties:
-OH group
CnH2n+1
flammable
Alcohols uses:
fuel
solvents
cooking flames
scents and flavorings
production of alcohols:
hydration of ethene:
ethene + steam ——-> ethanol (phosphoric acid catalyst, 60 atm, 300 degrees)
small scale, fast, continuous, pure ethanol produces, non- renewable resources used
Fermentation of glucose:
glucose ——-> ethanol + carbon dioxide (yeast enzyme used)
large scale, slow, batch process, impure alcohol produced, renewable resources used
Reactions of alcohols:
combustion
oxidation
dehydration
Carboxylic acid general properties:
-COOH group
weak acids
CnH2n+1COOH
What is Esterification?
Carboxylic acid + alcohol <—> ester + water
How do you draw an ester?
carboxylic acid first then functional group then alcohol.