Chapter 10: Acids and Bases Flashcards

1
Q

Arrhenius acid

A

dissociate to form an excess of H+

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2
Q

Arrhenius base

A

dissociate to form an excess of OH-

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3
Q

Bronsted-Lowry acid

A

donated hydrogen

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4
Q

Bronsted-Lowry base

A

accepts hydrogen

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5
Q

Lewis acid

A

electron acceptor

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6
Q

Strong acid + weak base

A

pH < 7

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7
Q

Strong acid + strong base

A

pH = 7

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8
Q

Weak acid + strong base

A

pH > 7

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9
Q

Autoionization constant for water

A

Kw = [H₃O⁺][OH⁻] = 1.0 x 10⁻¹⁴

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10
Q

Definition of pH and pOH

A

pH = – log [H+] = log 1 / [H+]

pOH = – log [OH–] = log 1 / [OH-]

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11
Q

Relationship of pH and pOH

A

pH + pOH = 14

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12
Q

Acid dissociation constant

A

Ka= [A^-] [H^+] / [HA]

Ka = acid dissociation constant
[A^-] = concentration of the conjugate base of the acid
[H+] = concentration of hydrogen ions
[HA] = concentration of chemical species HA

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13
Q

Base dissociation constant

A

Kb= [B^+] [OH^-]/ [BOH]

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14
Q

Equivalence point

A

Na Vb = Nb Va

Na and Nb are the acid and base normalities
Va and Vb are the volumes of acid and base solutions

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15
Q

Henderson - Hasselbalch Equation (acid buffer)

A

pH = pKa + log((A−)/(HA))

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16
Q

Henderson - Hasselbalch Equation (base buffer)

A

pOH = pKb + log((B+)/(BOH))