Chapter 10: Acids and Bases Flashcards
Arrhenius acid
dissociate to form an excess of H+
Arrhenius base
dissociate to form an excess of OH-
Bronsted-Lowry acid
donated hydrogen
Bronsted-Lowry base
accepts hydrogen
Lewis acid
electron acceptor
Strong acid + weak base
pH < 7
Strong acid + strong base
pH = 7
Weak acid + strong base
pH > 7
Autoionization constant for water
Kw = [H₃O⁺][OH⁻] = 1.0 x 10⁻¹⁴
Definition of pH and pOH
pH = – log [H+] = log 1 / [H+]
pOH = – log [OH–] = log 1 / [OH-]
Relationship of pH and pOH
pH + pOH = 14
Acid dissociation constant
Ka= [A^-] [H^+] / [HA]
Ka = acid dissociation constant
[A^-] = concentration of the conjugate base of the acid
[H+] = concentration of hydrogen ions
[HA] = concentration of chemical species HA
Base dissociation constant
Kb= [B^+] [OH^-]/ [BOH]
Equivalence point
Na Vb = Nb Va
Na and Nb are the acid and base normalities
Va and Vb are the volumes of acid and base solutions
Henderson - Hasselbalch Equation (acid buffer)
pH = pKa + log((A−)/(HA))