Chapter 10 Flashcards
____ was created because internationally there were different methods of both labeling and safety data sheets
GHS
Globally Harmonized System
OSHA adopted GHS through the hazard communication standard. It became mandatory as of June 1, 2015, and can be summarized into 3 main components
- Standardized hazard definitions and symbols
- Standardized MSDS format and content, which will be called SDSs
- Standardized hazard warnings and symbols on container labels
Pictography
There are 9 pictograms under GHS
Used as a primary element to communicate important information about the hazards of a chemical
Labels must have hazard pictograms framed in a red square frame set at a point (like a diamond)
Labeling
Responders may find both NFPA and GHS labeling. Only the GHS will be regulated
Hazard rating
Both NFPA and GHS have standard numerical ranking hazard levels
NFPA has 5 levels and the scale ranges from 0-4 and ranks 0 as the lowest hazard level
GHS has 4 levels and the scale ranges from 1-4 and ranks 1 as the highest hazard level
Signal words
A single word used to indicate the relative level of severity of hazard and alert the reader to a potential hazard on the label
Words are
Danger and warning
Danger is for the more severe hazards
Warning is for less severe hazard
SDS has how many sections?
16 sections
OSHA states that through GHS,
The standard that gave workers the right to know, now gives them the right to understand
OSHA through HazCom 2012 and NFPA are 2 separate and distinct systems
HazCom 2012 looks at hazmat from the perspective of informing workers about the hazards in a work place under normal conditions for the use of foreseeable emergencies
NFPA provides basic information for emergency personnel responding to fire or spills and planning for emergency response
The NFPA marking system _______ is required at facilities storing hazmat where referenced by fire code or other documents
NFPA 704
What do the NFPA markings stand for
Left quadrant blue: health hazard
Top quadrant red: flammability hazard
Right quadrant yellow: reactivity hazard
Bottom quadrant: special designation
A vehicle carrying hazmat should have placards that contain _____ identifying the product it is transporting
4 digit identification number
All modes of transportation are required to have shipping papers identifying their cargo. These papers are referred to differently, depending on the mode of transportation
Highway vehicle
Trains
Ships
Airplanes
Highway vehicle: bills of lading
Trains: way bills, wheel reports, consists
Ships: cargo manifest
Airplanes: air bills
If shipping papers cannot be located or if more information is needed, ______ can be called
CHEMTREC
Chemical transportation emergency center
A ready resource for assisting firefighters in identifying hazmat is provided by USDOT in its
ERG
Emergency response guidebook
Size consideration for setting up hot, warm and cold zones should be based upon
Wind direction
Terrain
Accessibility
Vapor clouds
Any explosion potential
If fire is in or impinging upon a vessel or tank, cooling of that container should be an immediate concern. This action will reduce the possibility of
A BLEVE
Boiling Liquid Expanding Vapor Explosion
A staging area for hazmat should be designated, considering
Topography
Wind
Accessibility
Contamination can be caused by
Chemical, Biological, Radiological exposures
_______ or ________ contamination will not be visible to the human eye.
Biological or radiological
Biological contamination is impossible to detect since it will not manifest itself until an incubation period has passed
Radiation can be detected through monitoring
If contaminated water enters the sewer system, the ______ must be notified
Water treatment plant
Involves highly flammable products and there is the ever present danger of rapid incident scene changes
Tank farm / refinery fires
There are 3 common types of flammable liquid storage tanks
- Open top floating roof
- Covered floating roof
- Cone roof
- Open top floating roof
- Covered floating roof
- Cone roof
- Open top floating roof
Designed to prevent buildup of vapors between the surface of the liquid and the underside of the roof
Most fire are located in the seal area
Identify by wind girder encircling it at the top
Fires that involve seal area should be fought with foam - Covered floating roof
Can be distinguished by vents near the top of the tank
Free of ignitable vapors except during filling and 1 day after
Fires in this tank are caused by an ignition source such as lightning - Cone roof
Acts the same as a covered roof, except the roof can separate and propel a distance from the tank when an explosion occurs
_____ is the most common firefighting agent used on tank fires
Water