CGP EXAM QUESTIONS: EL Flashcards

1
Q

Hydrogen, deuterium and tritium are all isotopes of each other

Identify one similarity and one difference between these isotopes

A

Similarity: All have same number of protons and electrons
Difference: All have different numbers of neutrons therefore different mass numbers

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2
Q

Hydrogen, deuterium and tritium are all isotopes of each other

Deuterium can be written as 2H. Determine the number of protons, neutrons and electrons in a neutral deuterium atom.

A

1 proton
1 neutron
1 electron

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3
Q

Hydrogen, deuterium and tritium are all isotopes of each other

Write the nuclear symbol for tritium, given that is has two neutrons

A

3H

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4
Q

Identify and explain the similarity between

A

32S2- has 16 + 2 = 18 electrons
40Ar has 18 electrons as well

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5
Q

Identify and explain the similarity between

A

Same number of protons
Each has 16 protons (atomic number of S must always be the same)
Isotopes - because have same number of protons but different numbers of neutrons therefore different mass numbers

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6
Q

Identify and explain the similarity between

A

Same number of neutrons
Ar = 40 - 18 = 22 neutrons
Ca = 42 - 20 = 22 neutrons

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7
Q

Scientific theories are constantly being revised in the light of new evidence. New theories are accepted because they have been successfully tested by experiments or because they help to explain certain observations
Niels Bohr thought that the model of the atom proposed by Ernest Rutherford did not describe the electrons in an atom correctly.

Why did he think this and how was his model of the atom different from Rutherford’s?

A

Bohr knew that if an electron was freely orbiting the nucleus it would spiral into it, causing the atom to collapse
His model only allowed electrons to be in fixed shells and not between them

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8
Q

Scientific theories are constantly being revised in the light of new evidence. New theories are accepted because they have been successfully tested by experiments or because they help to explain certain observations
Niels Bohr thought that the model of the atom proposed by Ernest Rutherford did not describe the electrons in an atom correctly.

According to the Bohr model of the atom, what happens when electrons in an atom move from one shell to another?

A

When an electron moves from one shell to another electromagnetic radiation is emitted or absorbed

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9
Q

Scientific theories are constantly being revised in the light of new evidence. New theories are accepted because they have been successfully tested by experiments or because they help to explain certain observations
Niels Bohr thought that the model of the atom proposed by Ernest Rutherford did not describe the electrons in an atom correctly.

How did the Bohr model explain the lack of reactivity of the noble gases?

A

The shells of an atom can only hold fixed numbers of electrons.

Noble gases have full shells and so do not react
OR a full shell of electrons makes an atom stable; noble gases have full shells and do not react because they are stable

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10
Q

Copper exists in two main isotopic forms, 63Cu and 65Cu

Calculate the relative atomic mass of copper

(where is the mass spectrum)

A
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11
Q

Copper exists in two main isotopic forms, 63Cu and 65Cu

Explain why the relative atomic mass of copper may not be a whole number

A

A sample of copper is a mixture of 2 isotopes of different abundances. The average mass of these isotopes isn’t a whole number

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12
Q

The percentage make-up of naturally occuring sulfur is 0.752% of 33S, 4.25% of 34S and 0.0110% of 36S, and the rest is 32S.

What method is used to determine the mass and abundance of each isotope?

A

mass spectrometry

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13
Q

The percentage make-up of naturally occuring sulfur is 0.752% of 33S, 4.25% of 34S and 0.0110% of 36S, and the rest is 32S.

Use the information to determine the relative atomic mass of sulfur

A

% of 32S = 100 - 0.752 - 4.25 - 0.0110 = 94.887

  1. 887 x 32 = 3039.584
  2. 752 x 33 = 24.816
  3. 25 x 34 = 144.5
  4. 0110 x 36 = 0.396

3039.584 + 24.816 + 144.5 + 0.396 = 3209.296
Ar of S = 3209.296/100 = 32.1
* divide by 100 because working with percentages

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14
Q

Calculate the mass of propene required to produce 49.2g of bromopropane:
C3H6 + HBr –> C3H7Br

A

M of C3H7Br = (3 x 12) + (7 x 1) + (1 x 79.9) = 122.9g

Number of moles of C3H7Br = 49.2/122.9 = 0.400 moles

From the equation, 1 mole of C3H7Br is made from 1 mole of C3H6 so, 0.400 moles C3H7Br is made from 0.400 moles C3H6

M of C3H6 = (3 x 12) + (6 x 1) = 42g
so the mass of 0.400 moles C3H6 = 0.400 x 42 = 16.8g

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15
Q

Balance the equation:

KI + Pb(NO3)2 –> PbI2 + KNO3

A

2KI + Pb(NO3)2 –> PbI2 + 2KNO3

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16
Q
Calcium carbonate (CaCO<sub>3</sub>) reacts with nitric acid (HNO<sub>3</sub>) in a neutralisation reaction. 
The products are carbon dioxide, water and a solution of calcium nitrate (Ca(NO<sub>3</sub>)<sub>2</sub>)

Write the balanced equation for this reaction

A

CaCO3(s) + 2HNO3(aq) –> Ca(NO3)2(aq) + CO2(g) + H2O(l)

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17
Q
Calcium carbonate (CaCO<sub>3</sub>) reacts with nitric acid (HNO<sub>3</sub>) in a neutralisation reaction. 
The products are carbon dioxide, water and a solution of calcium nitrate (Ca(NO<sub>3</sub>)<sub>2</sub>)

Calculate the volume of 1.50 mol dm-3 HNO3 needed to neutralise 1.84g of CaCO3

A

M of CaCO3 = 40.1 + 12 + (3 x 16) = 100.1 g mol-1

Moles of CaCO3 = 1.84/100.1 = 0.0184 moles

From equation : 1 mole of CaCO3 neutralises 2 moles of HNO3, so 0.0184 moles of CaCO3 neutralises 0.0368 moles of HNO3

Volume of HNO3 = (number of moles/concentration) x 1000
= (0.0368/1.50) x 1000 = 24.5 cm3

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18
Q

Hydrocarbon X has a molecular mass of 78.0g mol-1. It is found to have 92.3% carbon and 7.70% hydrogen by mass. Calculate the empirical and molecular formulae of X.

A

(Assume you have 100g of the compound)
No. of moles of C = 92.3/12 = 7.69 moles
No. of moles of H = 7.7/1 = 7.7 moles

Divide both by the smallest number - 7.69
So ration C : H = 1 : 1
So empirical formula = CH

Mass of atoms in the empirical formula = 12 + 1 = 13
No. of empirical units in molecule = 78/13 = 6
So molecular formula = C6H6

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19
Q

When 1.2g of magnesium ribbon is heated in air, it burns to form a white powder, which has a mass of 2g. What is the empirical formula of the powder?

A

Magnesium is burning, so its reacting with oxygen and the product is magnesium oxide
First work out the number of moles of each element

No. of moles Mg = 1.2/24 = 0.005 moles
Mass of O is everything that isn’t Mg = 2 - 1.2 = 0.8g
No. of moles O = 0.8/16 = 0.05 moles
Ratio Mg : O = 1 : 1
So empirical formula is MgO

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20
Q

When 19.8g of an organic acid, A, is burnt in excess oxygen, 33.0g of carbon dioxide and 10.8g of water are produced. Calculate the empirical formula for A and hence its molecular formula, if Mr (A) = 132.

A

First calculate the no. of moles of each product then the mass of C and H:

No. of moles of CO2 = 33/44 = 0.75 moles
Mass of C = 0.75 x 12 = 9g
No. of moles of H2O = 10.8/18 = 0.6 moles

0.6 moles H2O = 1.2 moles H
Mass of H = 1.2 x 1 = 1.2g
Organic acids contain C, H and O, so the rest of the mass must be O
Mass of O = 19.8 - (9 + 1.2) = 9.6g
No. of moles of O = 9.6/16 = 0.6 moles

Moles ratio = C : H : O = 0.75 : 1.2 : 0.6
Divide by smallest
C : H : O = 1.25 : 2 : 1
carbon part of ration isn’t a whole number, so you have to multiply them all up until it is. As its fraction is 5/4 multiply all by 4.
So mole ration = C : H : O = 5 : 8 : 4
Empirical formula = C5H8O4

Empirical mass = (12 x 5) + (1 x 8) + (16 x 4) = 132g
This is the same as what we’re told the molecular mass is, so the molecular formual is also C5H8O4

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21
Q

42.9g of CuSO4x H2O is heated until all the water has been driven off, leaving 27.3g of anhydrous copper sulfate. What is the value of x ?

A

M of CuSO4 = 63.5 + 32.1 + (4 x 16) = 159.6 g mol-1

No. of moles of CuSO4 = 27.3/159.6 = 0.171 moles

Mass of water = 42.9 - 27.3 = 15.6g
Moles of water = 15.6/18 = 0.867 moles
Divide by smallest:

Cu: 0.171/0.171 = 1
H2O: 0.867/0.171 = 5.07
So the value of x is 5
(the formula is CuSO4•5H2O)

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22
Q

The equation below shows the reaction for the complete combustion of propene
C3H6 + O2 –> CO2 + H2O

If the reaction of 91.3g of C3H6 produces an 81.3% yield, how many grams of CO2 would be produce?

A

First need to balance equation:
2C3H6 + 9O2 –> 6CO2 + 6H2O

M of C3H6 = (3 x 12) + (6 x 1) = 42g mol-1
moles of C3H6 = 91.3/42 = 2.17 moles

From equation; 2 moles of C3H6 produce 6 moles of CO2, so 2.17 moles of C3H6 produce (2.17/2) x 6 = 6.52 moles of CO2

M of CO2 = 12 + (2 x 16) = 44g mol-1
So theoretical yield = 6.52 x 44 =287g
Actual yield = (percentage yield x theoretical yield)/100
Actual yield = (81.3 x 287)/100
= 233g

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23
Q

Calculate the volume of 1 mol dm-3 hydrochloric acid solution needed to make 500cm3 of 0.5 mol dm-3 hydrochloric acid solution

A

Volume = (0.5/1) x 500
= 250cm3

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24
Q

Describe how indicators are used and explain the importance of selecting an appropriate indicator when carrying out a titration. Include examples of indicators that would and would not be suitable for use in titrations.

A

5-6 marks: The answer explains how indicators are used and includes at least one suitable and one unsuitable indicator for acid/alkali titrations with reasoning. The answer has a clear and logical structure. The information given is relevant and detailed

3-4 marks: The answer explains how indicators are used and includes one example of a suitable or unsuitable indicator for acid/alkali titrations. The answer has some structure. Most of the information given is relevant and there is some detail included.

1-2 marks: The answer contains some explanation of how indicators are used but gives no examples of indicators for acid/alkali titrations. The answer has no clear structure. The information given is basic and lacking in detail. It may not all be relevant.

Points answer may include:
Indicators change colour when the solution reaches a particular pH to mark an endpoint. They are used in acid/alkali titrations to mark the end point of the reaction. Indicators used in titrations need to change colour quickly over a very small pH range. A few drops of indicator solution are added to analyte. The analyte/indicator solution can be placed on a white surface to make a colour change easy to see. Methyl orange and phenolphthalein are both good indicators for titrations as they quickly change colour when the solution turns from alkali to acid. Universal indicator is a poor indicator to use for titrations as its colour changes gradually over a wide pH range.

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25
Q

Calculate the concentration (in mol dm-3) of a solution of ethanoic acid, CH3COOH, if 25.4 cm3 of it is neutralised by 14.6 cm3 of 0.500 mol dm-3 sodium hydroxide solution

CH3COOH + NaOH –> CH3COONa + H2O

A

CH3COOH + NaOH –> CH3COONa + H2O

No. of moles of NaOH = (0.500 x 14.6)/1000 = 0/00730 moles
From the equation, you know 1 mole of NaOH neutralises 1 mole of CH3COOH, so if you’ve used 0.00730 moles NaOH you must have neutralised 0.00730 moles CH3COOH

Concentration of CH3COOH = (0.00730/25.4) x 1000 = 0.287 mol dm-3

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26
Q

You are supplied with 0.750g of calcium carbonate and a solution of 0.250 mol dm-3 sulfuric acid. What volume of acid will be needed to neutralise the calcium carbonate?

CaCO3 + H2SO4 –> CaSO4 + H2O + CO2

A

CaCO3 + H2SO4 –> CaSO4 + H2O + CO2

M of CaCO3 = 40.1 + 12 + (3 x 16) = 100.1 g mol-1
Number of moles of CaCO3 = 0.750/100.1
= 7.49 x 10-3 moles

From the equation, 1 mole CaCO3 reacts with 1 mole H2SO4 so, 7.49 x 10-3 moles of CaCO3 reacts with 7.49 x 10-3 moles H2SO4

The volume needed is ((7.49 x 10-3)/0.250)) x 1000
= 30.0 cm3

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27
Q

In a titration, 17.1 cm3 of 0.250 mol dm-3 hydrochloric acid neutralises 25.0 cm3 calcium hydroxide solution

Write out a balanced equation for this reaction

A

Ca(OH)2 + 2HCl –> CaCl2 + 2H2O

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28
Q

In a titration, 17.1 cm3 of 0.250 mol dm-3 hydrochloric acid neutralises 25.0 cm3 calcium hydroxide solution

Work out the concentration of the calcium hydroxide solution

A

Ca(OH)2 + 2HCl –> CaCl2 + 2H2O

Number of moles of HCl = (0.250 x 17.1)/1000
= 4.275 x 10-3 moles

From equation , 2 moles HCl reacts with 1 mole Ca(OH)2 so, 4.275 x 10-3 moles HCl reacts with 2.1375 x 10-3 moles Ca(OH)2

So concentration of Ca(OH)2 solution = ((2.1375 x 10-3)/25.0) x 1000
= 0.0855 mol dm-3

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29
Q

Potassium reacts with oxygen to form potassium oxide, K2O

Give the electron configurations of the K atom and the K+ ion

A

K atom: 1s22s22p63s23p64s1 or [Ar] 4s1
K+ ion: 1s22s22p63s23p6 or [Ar]

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30
Q

Potassium reacts with oxygen to form potassium oxide, K2O

Give the electron configuration of the oxygen atom

A

1s22s22p4

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31
Q

What is the electron configuration of a manganese atom?

A

1s22s22p63s23p63d54s2 or [Ar] 3d54s2

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32
Q

Identify the element with the 4th shell configuration of 4s24p2

A

Germanium

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33
Q

Suggest the identity of an atom, a positive ion and a negative ion with the configuration 1s22s22p63s23p6

A

Ar (atom)
K+ (positive ion)
Cl- (negative ion)

Could have also suggested Ca2+ , S2- or P3- etc.

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34
Q

Give the electron configuration of the Fe+ ion

A

1s22s22p63s23p63d6

35
Q

Draw a labelled diagram to show the structure of sodium chloride. Include at least 12 ions

A

Diagram should include:
cubic structure with ions at corners
sodium ions and chloride ions labelled
alternating sodium ions and chloride ions

36
Q

What is the name of the structure that sodium chloride has?

A

giant ionic (lattice)

37
Q

Would you expect sodium chloride to have a high or a low melting point? Explain your answer.

A

You’d expect it to have a high melting point
Because there are strong bonds between the ions due to the electrostatic forces. A lot of energy is required to overcome these bonds

38
Q

Ions can be formed by electron transfer

Explain this and give an example for a positive and a negative ion

A

Electrons move from one atom to another
Any correct examples of ions, one positive, one negative.
E.g. Na+ , Cl-

39
Q

Solid lead bromide does not conduct electricity, but molten lead bromide does. Explain this with reference to ionic bonding.

A

In a solid, ions are held in place by strong ionic bonds
When the solid is heated to melting point, the ions gain enough energy to overcome the forces of attraction and become mobile, so can carry charge (and hence electricity) through the substance

40
Q

Which is the correct formula for aluminium chloride?

A) AlCl

B) Al2Cl3

C) Al3Cl

D) AlCl3

A

D

Aluminium is in Group 3, so it loses 3 electrons to become an aluminium ion Al3+
Chlorine is in Group 7, so it gains 1 electron to become chloride ion Cl-
You need three chloride ions to balance the 3+ charge on the aluminium ion, so the formula of aluminium chloride is AlCl3

41
Q

Draw a dot-and-cross diagram (showing outer shell electrons only) to represent the bonding in the molecule silicon hydride (SiH4)

A
42
Q

Describe two physical properties that you would expect silicon hydride to exhibit.

A

E.g. Non-conductor of electricity (no free electrons)
Low melting point (simple molecular, non-polar molecule - like methane)

43
Q

Methane melts at -183oC. Magnesium oxide melts at 2800oC
Explain this difference in terms of bonding

A

Methane is a simple molecular substance
When it melts only weak intermolecular forces are overcome
Magnesium oxide is ionic
so to melt it the strong electrostatic attractions must be broken, which requires more energy/higher temperatures

44
Q

Draw a dot-and-cross diagram of the ammonia molecule (NH3) showing the outer shell electrons only

A
45
Q

Draw a dot-and-cross diagram of the hydrogen chloride molecule (HCl) showing the outer shell electrons only.

A
46
Q

Ammonia reacts with hydrogen chloride to form ammonium chloride. Draw a dot-and-cross diagram to show the bonding in ammonium chloride.

A
47
Q

Predict whether ammonium chloride is likely to be soluble or insoluble in water

A

Ammonium chloride is likely to be soluble in water. The polar water molecules can break apart an ionic lattice

48
Q

Explain what is meant by metallic bonding. Draw a diagram to illustrate your explanation.

A

Metallic bonding results from the attraction between positive metal ions and a sea of delocalised electrons between them

49
Q

Explain why calcium has a higher melting point than potassium

A

Calcium (Ca2+) has two delocalised electrons per atom, while potassium (K+) has only one delocalised electron per atom. So calcium has more delocalised electrons and therefore stronger metallic bonding.

50
Q

Carbon dioxide is a covalent compound that sublimes (turns directly from a solid to a gas) at -78oC. Silicon dioxide is a covalent compound that melts at 1610oC.

Explain these differences in terms of bonding.

A

Carbon dioxide is a simple molecular substance
Covalent bonds between carbon and oxygen are strong but when carbon dioxide sublimes it is the weak intermolecular forces that are overcome.
Silicon dioxide has a giant covalent lattice structure, so to melt it the strong covalent bonds must be broken, which requires more energy/higher temperatures

51
Q

Graphite is a giant covalent structure. However, unlike most giant covalent structures, it is able to conduct electricity. Explain why graphite is able to conduct electricity.

A

Graphite consists of sheets of carbon atoms, where each carbon atom is bonded to three others. This means that each atom has one free electron not involved in bonds, it is these free electrons that allow graphite to conduct electricity.

52
Q

Electrical grade copper must be 99.9% pure. If sulfur and oxygen impurities react with the copper ions, its electrical conductivity is drastically reduced. Use your knowledge of metallic and ionic bonding to explain this.

A

Copper is metallically bonded and so delocalised electrons are free to move (carry electric current). Oxygen and sulfur form copper oxide/sulfide, fixing some electrons (as anions). This prevents them from moving and carrying charge.

53
Q

Carborundum (silicon carbide) has the formula SiC and is almost as hard as diamond

What sort of structure would you expect carborundum to have as a solid?

A

Giant covalent

54
Q

Carborundum (silicon carbide) has the formula SiC and is almost as hard as diamond

Apart from hardness, give two other physical properties you would expect carborundum to have.

A

Any 2 from:

high melting point
electrical non-conductor (insulator)
insoluble
good thermal conductor

55
Q

Nitrogen and boron can form the chlorides NCl3 and BCl3

Draw the shape of NCl3 and label it with the name of the shape and the approximate values of the bond angles.

A

shape: trigonal pyramidal
bond angle: 107o

56
Q

Nitrogen and boron can form the chlorides NCl3 and BCl3

Draw the shape of BCl3 and label it with the name of the shape and the approximate values of the bond angles.

A

shape: trigonal planar
bond angle: 120o exactly

57
Q

Nitrogen and boron can form the chlorides NCl3 and BCl3

Explain why the shapes of NCl3 and BCl3 are different

A

BCl3 has three electron pairs only around B
NCl3 has four electron pairs around N, including one lone pair

58
Q

The displayed formula of an organic compound is shown. Use electron pair repulsion theory to predict the shape and relevant bond angles of the bond around atoms A,B and C. Give reasons for your answers.

A

Atom A: shape: trigonal planar
bond angle: 120o exactly
2 single bonds and 1 double bond

Atom B: shape: tetrahedral
bond angle: 109.5o
4 bonding pairs

Atom C: shape; non-linear, bent
bond angle: 104.5o
2 bonding pairs and 2 lone pairs

59
Q

The graph shows first ionisation enthalpy plotted against atomic number. Which of the labelled points on the graph shows the first ionisation enthalpy of a Group 2 metal?

A

C

60
Q

The graph shows first ionisation enthalpy plotted against atomic number. Which of the labelled points on the graph shows the first ionisation enthalpy of an element with a full outer electron shell?

A

B

61
Q

The graph shows first ionisation enthalpy plotted against atomic number. Which of the labelled points on the graph shows the first ionisation enthalpy of an element in Period 3?

A

C

62
Q

Explain why first ionisation energies show an overall tendency to increase across a period.

A

As you move across a period, the number of protons increases, meaning a stronger pull from the positively charged nucleus
making it harder to remove an electron from the outer shell
There are no extra inner electrons to add to the shielding effect

63
Q

Explain why the melting point of magnesium is higher than that of sodium

A

Mg has more delocalised electrons per atom
and the ion has a greater charge density
This give Mg a stronger metal-metal bond, resulting in a higher melting point

64
Q

State and explain the trend in the first ionisation enthalpy of Group 2 elements

A

First ionisation enthalpy decreases down Group 2
because the outer electrons are in shells further from the nucleus
The amount of shielding also increases because there are more filled inner shells
Both of these decrease the nuclear attraction for the outer shell electrons

65
Q

Barium and calcium are both Group 2 elements.

Which of the two ions has the highest charge density

A

Calcium (Ca2+)

66
Q

Barium and calcium are both Group 2 elements

Write a balanced equation for thermal decomposition of calcium carbonate including state symbols

A

CaCO3(s) –> CaO(s) + CO2(g)

67
Q

Barium and calcium are both Group 2 element
They both form carbonates

State whether barium carbonate or calcium carbonate is more thermally stable. Explain your answer.

A

Barium carbonate is more thermally stable
This is because barium has a lower charge density than calcium, so it has weaker polarising power
The weaker polarising power of the barium ion causes less distortion of the carbonate ion (making it more thermally stable)

68
Q

Write a balanced equation for the reaction of magnesium hydroxide with dilute hydrochloric acid

A

Mg(OH)2 + 2HCl –> MgCl2 + 2H2O

69
Q

Write a balanced equation for the reaction of calcium oxide with water

A

CaO + H2O –> Ca2+ + 2OH-

or

CaO + H2O –> Ca(OH)2

70
Q

Explain why calcium hydroxide is a stronger alkali than magnesium hydroxide

A

Calcium hydroxide is more soluble in water than magnesium hydroxide, and so dissociation produces a higher concentration of hydroxide ions in solution

71
Q

What is the formula of the soluble salt produced in the reaction between nitric acid and copper(II) hydroxide?

A) NO3Cu2

B) CuOH2

C) H2NO3

D) Cu(NO3)2

A

D) Cu(NO3)2

72
Q

Which of the following compounds would react with iron(III) chloride to produce an insoluble salt?

A) sodium chloride

B) silver nitrate

C) copper(II) sulfate

D) calcium sulfate

A

B) silver nitrate

73
Q

Potassium sulfate can be made by mixing potassium hydroxide with sulfuric acid.

Describe the method you would use to produce pure, solid potassium sulfate in the lab.

A

Titrate some potassium hydroxide with a known volume of sulfuric acid and add some drops of indicator to show when the reaction’s finished
Then repeat titration using the same amount of acid and the exact amount of potassium hydroxide needed to neutralise it, so the salt isn’t contaminated with indicator
To get pure potassium sulfate, evaporate some of the water and then leave the rest to evaporate very slowly

74
Q

Describe a test that can be used to test for carbonates in a solution

A

Add dilute hydrochloric acid to the solution
and then test to see whether the gas giveon off is carbon dioxide by bubbling it through limewater
if limewater goes cloudy, the solution contains carbonates

75
Q

What colour flame would be produced from a solution of potassium iodide?

A) yellow

B) brick red

C) lilac

D) crimson

A

C) lilac

76
Q

What colour precipitate would be produced from the reaction of calcium carbonate and sodium hydroxide?

A) brick red

B) white

C) blue

D) cream

A

B) white

77
Q

A student is given a solution of iron(II) sulfate.

Describe how the student could prove that the solution actually is iron(II) sulfate

A

Add a few drops of sodium hydroxide to a sample of the solution.
If a green precipitate forms, then iron(II) ions are present
Then add HCl followed by barium chloride solution to a sample of the solution. A white precipitate will form if sulfate ions are present.

78
Q

The diagram below shows part of an atomic absorption spectrum of a single element.

What happens in the atom when radiation is absorbed?

A

The movement of electrons/an electron from lower to higher energy levels

79
Q

The diagram below shows part of an atomic absorption spectrum of a single element.

Which line in the spectrum represents the largest absorption of energy?

A

Line E (because it is at the highest frequency)

80
Q

The diagram below shows part of an atomic absorption spectrum of a single element.
The same element is used to produce an atomic emission spectrum

What would be different about this spectrum?

A

It would consist of bright, not dark, lines

81
Q

The diagram below shows part of an atomic absorption spectrum of a single element.
The same element is used to produce an atomic emission spectrum

What would be the same about the lines in the two spectra?

A

The lines would be at the same frequencies

82
Q

The diagram below shows part of an atomic absorption spectrum of a single element.

Explain why the lines get closer together from A to E

A

Because the energy levels get closer together with increasing energy

83
Q

The emission spectrum of the element sodium shows a set of lines in the visible part of the spectrum.
There is a strong line at a frequency 5.10 x 1014 Hz, which corresponds to the colour yellow

What is the energy of the electron transition responsible for this line?
(Planck’s constant = 6.63 x 10-34 J Hz-1)

A

Use E =hv
E = (6.63 x 10-34) x (5.1 x 1014) = 3.38 x 10-19 J

84
Q

The emission spectrum of the element sodium shows a set of lines in the visible part of the spectrum.
​There is a strong line at a frequency 5.10 x 1014 Hz, which corresponds to the colour yellow.

What is the wavelength of the radiation emitted?
(Speed of electromagnetic radiation = 3.00 x 108 m/s)

A

Use c = vλ
λ = c/v = (3.00 x 108)/(5.10 x 1014)
= 5.88 x 10-7 m/s