CGP EXAM QUESTIONS: EL Flashcards
Hydrogen, deuterium and tritium are all isotopes of each other
Identify one similarity and one difference between these isotopes
Similarity: All have same number of protons and electrons
Difference: All have different numbers of neutrons therefore different mass numbers
Hydrogen, deuterium and tritium are all isotopes of each other
Deuterium can be written as 2H. Determine the number of protons, neutrons and electrons in a neutral deuterium atom.
1 proton
1 neutron
1 electron
Hydrogen, deuterium and tritium are all isotopes of each other
Write the nuclear symbol for tritium, given that is has two neutrons
3H
Identify and explain the similarity between
32S2- has 16 + 2 = 18 electrons
40Ar has 18 electrons as well
Identify and explain the similarity between
Same number of protons
Each has 16 protons (atomic number of S must always be the same)
Isotopes - because have same number of protons but different numbers of neutrons therefore different mass numbers
Identify and explain the similarity between
Same number of neutrons
Ar = 40 - 18 = 22 neutrons
Ca = 42 - 20 = 22 neutrons
Scientific theories are constantly being revised in the light of new evidence. New theories are accepted because they have been successfully tested by experiments or because they help to explain certain observations
Niels Bohr thought that the model of the atom proposed by Ernest Rutherford did not describe the electrons in an atom correctly.
Why did he think this and how was his model of the atom different from Rutherford’s?
Bohr knew that if an electron was freely orbiting the nucleus it would spiral into it, causing the atom to collapse
His model only allowed electrons to be in fixed shells and not between them
Scientific theories are constantly being revised in the light of new evidence. New theories are accepted because they have been successfully tested by experiments or because they help to explain certain observations
Niels Bohr thought that the model of the atom proposed by Ernest Rutherford did not describe the electrons in an atom correctly.
According to the Bohr model of the atom, what happens when electrons in an atom move from one shell to another?
When an electron moves from one shell to another electromagnetic radiation is emitted or absorbed
Scientific theories are constantly being revised in the light of new evidence. New theories are accepted because they have been successfully tested by experiments or because they help to explain certain observations
Niels Bohr thought that the model of the atom proposed by Ernest Rutherford did not describe the electrons in an atom correctly.
How did the Bohr model explain the lack of reactivity of the noble gases?
The shells of an atom can only hold fixed numbers of electrons.
Noble gases have full shells and so do not react
OR a full shell of electrons makes an atom stable; noble gases have full shells and do not react because they are stable
Copper exists in two main isotopic forms, 63Cu and 65Cu
Calculate the relative atomic mass of copper
(where is the mass spectrum)
Copper exists in two main isotopic forms, 63Cu and 65Cu
Explain why the relative atomic mass of copper may not be a whole number
A sample of copper is a mixture of 2 isotopes of different abundances. The average mass of these isotopes isn’t a whole number
The percentage make-up of naturally occuring sulfur is 0.752% of 33S, 4.25% of 34S and 0.0110% of 36S, and the rest is 32S.
What method is used to determine the mass and abundance of each isotope?
mass spectrometry
The percentage make-up of naturally occuring sulfur is 0.752% of 33S, 4.25% of 34S and 0.0110% of 36S, and the rest is 32S.
Use the information to determine the relative atomic mass of sulfur
% of 32S = 100 - 0.752 - 4.25 - 0.0110 = 94.887
- 887 x 32 = 3039.584
- 752 x 33 = 24.816
- 25 x 34 = 144.5
- 0110 x 36 = 0.396
3039.584 + 24.816 + 144.5 + 0.396 = 3209.296
Ar of S = 3209.296/100 = 32.1
* divide by 100 because working with percentages
Calculate the mass of propene required to produce 49.2g of bromopropane:
C3H6 + HBr –> C3H7Br
M of C3H7Br = (3 x 12) + (7 x 1) + (1 x 79.9) = 122.9g
Number of moles of C3H7Br = 49.2/122.9 = 0.400 moles
From the equation, 1 mole of C3H7Br is made from 1 mole of C3H6 so, 0.400 moles C3H7Br is made from 0.400 moles C3H6
M of C3H6 = (3 x 12) + (6 x 1) = 42g
so the mass of 0.400 moles C3H6 = 0.400 x 42 = 16.8g
Balance the equation:
KI + Pb(NO3)2 –> PbI2 + KNO3
2KI + Pb(NO3)2 –> PbI2 + 2KNO3
Calcium carbonate (CaCO<sub>3</sub>) reacts with nitric acid (HNO<sub>3</sub>) in a neutralisation reaction. The products are carbon dioxide, water and a solution of calcium nitrate (Ca(NO<sub>3</sub>)<sub>2</sub>)
Write the balanced equation for this reaction
CaCO3(s) + 2HNO3(aq) –> Ca(NO3)2(aq) + CO2(g) + H2O(l)
Calcium carbonate (CaCO<sub>3</sub>) reacts with nitric acid (HNO<sub>3</sub>) in a neutralisation reaction. The products are carbon dioxide, water and a solution of calcium nitrate (Ca(NO<sub>3</sub>)<sub>2</sub>)
Calculate the volume of 1.50 mol dm-3 HNO3 needed to neutralise 1.84g of CaCO3
M of CaCO3 = 40.1 + 12 + (3 x 16) = 100.1 g mol-1
Moles of CaCO3 = 1.84/100.1 = 0.0184 moles
From equation : 1 mole of CaCO3 neutralises 2 moles of HNO3, so 0.0184 moles of CaCO3 neutralises 0.0368 moles of HNO3
Volume of HNO3 = (number of moles/concentration) x 1000
= (0.0368/1.50) x 1000 = 24.5 cm3
Hydrocarbon X has a molecular mass of 78.0g mol-1. It is found to have 92.3% carbon and 7.70% hydrogen by mass. Calculate the empirical and molecular formulae of X.
(Assume you have 100g of the compound)
No. of moles of C = 92.3/12 = 7.69 moles
No. of moles of H = 7.7/1 = 7.7 moles
Divide both by the smallest number - 7.69
So ration C : H = 1 : 1
So empirical formula = CH
Mass of atoms in the empirical formula = 12 + 1 = 13
No. of empirical units in molecule = 78/13 = 6
So molecular formula = C6H6
When 1.2g of magnesium ribbon is heated in air, it burns to form a white powder, which has a mass of 2g. What is the empirical formula of the powder?
Magnesium is burning, so its reacting with oxygen and the product is magnesium oxide
First work out the number of moles of each element
No. of moles Mg = 1.2/24 = 0.005 moles
Mass of O is everything that isn’t Mg = 2 - 1.2 = 0.8g
No. of moles O = 0.8/16 = 0.05 moles
Ratio Mg : O = 1 : 1
So empirical formula is MgO
When 19.8g of an organic acid, A, is burnt in excess oxygen, 33.0g of carbon dioxide and 10.8g of water are produced. Calculate the empirical formula for A and hence its molecular formula, if Mr (A) = 132.
First calculate the no. of moles of each product then the mass of C and H:
No. of moles of CO2 = 33/44 = 0.75 moles
Mass of C = 0.75 x 12 = 9g
No. of moles of H2O = 10.8/18 = 0.6 moles
0.6 moles H2O = 1.2 moles H
Mass of H = 1.2 x 1 = 1.2g
Organic acids contain C, H and O, so the rest of the mass must be O
Mass of O = 19.8 - (9 + 1.2) = 9.6g
No. of moles of O = 9.6/16 = 0.6 moles
Moles ratio = C : H : O = 0.75 : 1.2 : 0.6
Divide by smallest
C : H : O = 1.25 : 2 : 1
carbon part of ration isn’t a whole number, so you have to multiply them all up until it is. As its fraction is 5/4 multiply all by 4.
So mole ration = C : H : O = 5 : 8 : 4
Empirical formula = C5H8O4
Empirical mass = (12 x 5) + (1 x 8) + (16 x 4) = 132g
This is the same as what we’re told the molecular mass is, so the molecular formual is also C5H8O4
42.9g of CuSO4•x H2O is heated until all the water has been driven off, leaving 27.3g of anhydrous copper sulfate. What is the value of x ?
M of CuSO4 = 63.5 + 32.1 + (4 x 16) = 159.6 g mol-1
No. of moles of CuSO4 = 27.3/159.6 = 0.171 moles
Mass of water = 42.9 - 27.3 = 15.6g
Moles of water = 15.6/18 = 0.867 moles
Divide by smallest:
Cu: 0.171/0.171 = 1
H2O: 0.867/0.171 = 5.07
So the value of x is 5
(the formula is CuSO4•5H2O)
The equation below shows the reaction for the complete combustion of propene
C3H6 + O2 –> CO2 + H2O
If the reaction of 91.3g of C3H6 produces an 81.3% yield, how many grams of CO2 would be produce?
First need to balance equation:
2C3H6 + 9O2 –> 6CO2 + 6H2O
M of C3H6 = (3 x 12) + (6 x 1) = 42g mol-1
moles of C3H6 = 91.3/42 = 2.17 moles
From equation; 2 moles of C3H6 produce 6 moles of CO2, so 2.17 moles of C3H6 produce (2.17/2) x 6 = 6.52 moles of CO2
M of CO2 = 12 + (2 x 16) = 44g mol-1
So theoretical yield = 6.52 x 44 =287g
Actual yield = (percentage yield x theoretical yield)/100
Actual yield = (81.3 x 287)/100
= 233g
Calculate the volume of 1 mol dm-3 hydrochloric acid solution needed to make 500cm3 of 0.5 mol dm-3 hydrochloric acid solution
Volume = (0.5/1) x 500
= 250cm3
Describe how indicators are used and explain the importance of selecting an appropriate indicator when carrying out a titration. Include examples of indicators that would and would not be suitable for use in titrations.
5-6 marks: The answer explains how indicators are used and includes at least one suitable and one unsuitable indicator for acid/alkali titrations with reasoning. The answer has a clear and logical structure. The information given is relevant and detailed
3-4 marks: The answer explains how indicators are used and includes one example of a suitable or unsuitable indicator for acid/alkali titrations. The answer has some structure. Most of the information given is relevant and there is some detail included.
1-2 marks: The answer contains some explanation of how indicators are used but gives no examples of indicators for acid/alkali titrations. The answer has no clear structure. The information given is basic and lacking in detail. It may not all be relevant.
Points answer may include:
Indicators change colour when the solution reaches a particular pH to mark an endpoint. They are used in acid/alkali titrations to mark the end point of the reaction. Indicators used in titrations need to change colour quickly over a very small pH range. A few drops of indicator solution are added to analyte. The analyte/indicator solution can be placed on a white surface to make a colour change easy to see. Methyl orange and phenolphthalein are both good indicators for titrations as they quickly change colour when the solution turns from alkali to acid. Universal indicator is a poor indicator to use for titrations as its colour changes gradually over a wide pH range.
Calculate the concentration (in mol dm-3) of a solution of ethanoic acid, CH3COOH, if 25.4 cm3 of it is neutralised by 14.6 cm3 of 0.500 mol dm-3 sodium hydroxide solution
CH3COOH + NaOH –> CH3COONa + H2O
CH3COOH + NaOH –> CH3COONa + H2O
No. of moles of NaOH = (0.500 x 14.6)/1000 = 0/00730 moles
From the equation, you know 1 mole of NaOH neutralises 1 mole of CH3COOH, so if you’ve used 0.00730 moles NaOH you must have neutralised 0.00730 moles CH3COOH
Concentration of CH3COOH = (0.00730/25.4) x 1000 = 0.287 mol dm-3
You are supplied with 0.750g of calcium carbonate and a solution of 0.250 mol dm-3 sulfuric acid. What volume of acid will be needed to neutralise the calcium carbonate?
CaCO3 + H2SO4 –> CaSO4 + H2O + CO2
CaCO3 + H2SO4 –> CaSO4 + H2O + CO2
M of CaCO3 = 40.1 + 12 + (3 x 16) = 100.1 g mol-1
Number of moles of CaCO3 = 0.750/100.1
= 7.49 x 10-3 moles
From the equation, 1 mole CaCO3 reacts with 1 mole H2SO4 so, 7.49 x 10-3 moles of CaCO3 reacts with 7.49 x 10-3 moles H2SO4
The volume needed is ((7.49 x 10-3)/0.250)) x 1000
= 30.0 cm3
In a titration, 17.1 cm3 of 0.250 mol dm-3 hydrochloric acid neutralises 25.0 cm3 calcium hydroxide solution
Write out a balanced equation for this reaction
Ca(OH)2 + 2HCl –> CaCl2 + 2H2O
In a titration, 17.1 cm3 of 0.250 mol dm-3 hydrochloric acid neutralises 25.0 cm3 calcium hydroxide solution
Work out the concentration of the calcium hydroxide solution
Ca(OH)2 + 2HCl –> CaCl2 + 2H2O
Number of moles of HCl = (0.250 x 17.1)/1000
= 4.275 x 10-3 moles
From equation , 2 moles HCl reacts with 1 mole Ca(OH)2 so, 4.275 x 10-3 moles HCl reacts with 2.1375 x 10-3 moles Ca(OH)2
So concentration of Ca(OH)2 solution = ((2.1375 x 10-3)/25.0) x 1000
= 0.0855 mol dm-3
Potassium reacts with oxygen to form potassium oxide, K2O
Give the electron configurations of the K atom and the K+ ion
K atom: 1s22s22p63s23p64s1 or [Ar] 4s1
K+ ion: 1s22s22p63s23p6 or [Ar]
Potassium reacts with oxygen to form potassium oxide, K2O
Give the electron configuration of the oxygen atom
1s22s22p4
What is the electron configuration of a manganese atom?
1s22s22p63s23p63d54s2 or [Ar] 3d54s2
Identify the element with the 4th shell configuration of 4s24p2
Germanium
Suggest the identity of an atom, a positive ion and a negative ion with the configuration 1s22s22p63s23p6
Ar (atom)
K+ (positive ion)
Cl- (negative ion)
Could have also suggested Ca2+ , S2- or P3- etc.