carbs Flashcards

1
Q

tell the order of sweet sugars

A
lactose -0.15
maltose
glucose
sucrose
fructose
sucralose - 6
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2
Q

high molecular weight of soluble polymer is important for

A

viscosity of carbohydrate

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3
Q

what is glUcan

A

polysaccharide or carbohydrate part of glycoconjugate polymer of glucose

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4
Q

what is glYcan

A

any polysaccharides or oligosaccharide

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5
Q

what is glycome

A

total expressed glycan, more complex than Genome or proteom

can change the extrinsic and intrinsic responses

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6
Q

why only a limited number of genes are expressed from typical genome?

A

because glycome difference in cell type, space and time generate biological diversity

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7
Q

tell recognition role of glycans

A

glycans are recognised by specific glycan binding protein intrinsic to an organism
+ recognised by extrinsic bp in PATHOGENS and symbionts

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8
Q

tell the difference between L and D enantiomers

A

if the bottom OH on fisher projection is on the left - L

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9
Q

how Haworth formula from

A

right side of the fisher projection must be on the outside

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10
Q

tell the difference between pyranose and furanose rings

A

Pyranose- cyclic sugar rings containing 6 membrane rings

Furanose- 5 membrane rings

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11
Q

difference between D glucose and D fructose

A

D glucose has an aldehyde

D fructose has a kettle

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12
Q

what are epimers

A

any 2 sugars that differ only in configuration of a single chiral carbon

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13
Q

why glycans and sugars are important

A

because the size of the polymer and the degree of branching affects FUNCTIONALITY, SPECIFIC SEQUENCES which are recognised by enzymes

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14
Q

what are cyclodextrins

A

cyclic oligosaccharides result from cyclomaltodextrin glucantransferase

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15
Q

what are cyclotextrins used for

A
to remove cholesterol 
to stabilise volotile compounds
to increase water solubility 
reduction of unwanted tastes 
to improve light stability of delicate compounds
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16
Q

tell common polysaccharides and their structure

A

amylose ( alpha D glucose 1-4 to alpha D glucose )
cellulose ( beta D glucose 1-4 to beta D glucose )
chitin (beta D NAc glucosamine 1-4 to beta D Nac glucosamine)

17
Q

how chitin is different from cellulose

A

it has acetyl group on C2instead of OH

18
Q

tell main uses of polysaccharides

A

modified rheological and textural properties
stabilisations
control of lubricity
control of phase behaviour