Carboxylic Acids and its Derivatives Flashcards

1
Q

organic compoudns having hydroxyl group (-OH) attached to acyl gorup

A

carboxylic acids

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2
Q

group of atoms consisting of a carbonyl group attached to a carbon

A

acyl groups

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3
Q

Carboxylic acid derivatives contain functional groups that undergo nucleophilic acyl substitution and are called __ __

A

acyl derivatives

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4
Q

if we remove the hydroxyl group with a haloge, that will give us an __ __

A

acid halide

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5
Q

are the most reactive carboxylic acid derivative, which allow them to easily convert to other acyl compounds

A

acid chlorides

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6
Q

organic compound that has two acyl groups bound to the same oxygen atom

A

acid anhydride

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7
Q

OR group replaces OH group in carboxylic acid

A

ester

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8
Q

OH is replaced with nitrogen in carboxylic acid

A

amide

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9
Q

formation of ester

A

esterification

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10
Q

formation of amide

A

amidation

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11
Q

esterification

A

carboxylic acid + alcohol –> ester + water

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12
Q

amidation

A

carboxylic acid + amine –> amide + water

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13
Q

Two types of hydrolysis of amides

A
  1. acidic hydrolysis
  2. basic hydrolysis
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14
Q

product of acidic hydrolysis

A

amide + water + acid –> carboxylic acid + ammonium salt

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15
Q

product of basic hydrolysis

A

amide + water + base –> carboxylic ion + amine

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16
Q

Why do carboxylic acids have high boiling points than expected

A

they are capable of forming dimers

17
Q

polymer formed from two molecules of a monomer

A

dimer

18
Q

carboxylic acid

A

COOH

19
Q

ester

A

COOR

20
Q

acyl halide

A

COOX

21
Q

amide

A

COON

22
Q

nitrile

A

C≡N

23
Q

aldehyde

A

COH

24
Q

ketone

A

CO

25
Q

hierarchy nomenclature

A

carboxylic acid > ester> acyl halide> amide> nitrile> aldehyde> ketone> alcohol> thiol> amine> hydrocarbons