Aldehyde and Ketones Flashcards

1
Q

aldehydes and ketones are often called __ or __

A
  • formyl
  • methanoyl
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

aldehydes derive their name form the __ _ __

A

dehydration of alcohols

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

aldehydes contain the carbonyl group bonded to at least __ __ __

A

one hydrogen atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

ketones contain carbonyl group bonded to __ __ __

A

two carbon atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

IUPAC system of nomenclature assigns a characteristic suffix __ to aldehydes

A

-al

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

where should you start counting in aldehyde

A

starting at aldehyde group

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

when naming the parent chain of an aldehyde attached to a ring, the suffix __ is added to the end of the ring name

A

-carbaldehyde

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

6 carbon ring cyclohexane with aldehyde

A

cyclohexanecarbaldehyde

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

IUPAC system of nomenclature assigns a characteristic suffix __ to ketones

A

-one

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

where should you start counting in ketones

A

closest to the ketone group

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

aldehydes have a __ __ than ketones

A

higher priority

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

for dialdehydes the location numbers for both carbonyls are __

A

omitted

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

for diketones both carbonyl require a __ __

A

location number

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

in naming, the functional group with carbonyl is given the __ priority

A

Highest

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

when an aldehyde or ketone is present in a molecule which also contains alkene functional group, the carbonyl is given nomenclature __ by the IUPAC system

A

priority

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

fragment with carbonyl group

A

alkanoyl (acyl, older)

17
Q

group consisting of a carbonyl group bonded to a hydrogen atom

A

formyl

18
Q

group consisting of a carbonyl group bonded to CH3 fragment

A

acetyl

19
Q

monosaccharides containing aldehdyes are called __ and __ for ketones

A
  • aldose
  • ketose
20
Q

breakdown of fats that produce ketones

A

ketosis

21
Q

source of ketones from alkyne

A

hydration of alkynes

22
Q

other aldehydes and ketones continuing up to eleven carbon atoms are __ __ while stil higher members are __

A
  • colorless liquid
  • solids
23
Q

lower aldehydes have __ odors

A

unpleasant

24
Q

other aldehydes and ketones have a __ __

A

pleasant smell

25
Q

solubility of aldehydes and ketones up to 4 carbon atoms

A

soluble in water

26
Q

solubility of aldehydes and ketones __ by increasing the length of alkyl chain

A

decreases

27
Q

aldehydes and ketones have __ boiling point than non-polar compounds but have __ boiilng point than corresponding alcohols or carboxylic acids

A
  • higher (than hydrocarbons)
  • lower
28
Q

due to the presence of carbon-oxygen double bonds in aldehydes and ketones, they are __ in nature

A

polar

29
Q

Aldehydes and ketones can be prepared by a number of methods

A
  1. Hydration of alkynes
  2. Ozonolysis of certain alkenes
  3. Oxidation of Alcohols
30
Q

All alkynes react with water in the presence of HgSO4 and H2SO4 catalyst to yield an __

A

enol

31
Q

reaction method in which addition of ozone molecules or O3 to an alkene compound leads to the formation of ozonide

A

ozonolysis of alkenes

32
Q

addition of ozone molecules or O3 to an alkene compound leads to the formation of __

A

ozonide