Carbohydrates and molarity Flashcards

1
Q

How to chemical changes effect carbohydrates

A

Affects their function and the way the body uses them, the react differently with other molecules meaning they have different properties.

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2
Q

Glycosylation

A

In post translational modification oligosaccharides can be added to proteins. They can regulate protein function, can be O-linked (oxygen) or N-linked (nitrogen), Aids in folding and processing of protein, alters its ability to interact with other cell macromolecules.

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3
Q

Functions of glycosylation

A

They are involved in protection (mucin), recognition, adhesion, structural (collagen), and cell communication.

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4
Q

Three classes of glycoproteins

A

simple glycoproteins (mainly protein), mucins (mainly carbohydrate), proteoglycans (mainly carbohydrate).

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5
Q

Glycosylation diseases

A

Diseases can be caused when there is a mutation in the enzyme involved in glycosylation meaning the process does not take place. Can cause developmental delay and seizures.

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6
Q

Mucus function

A

Forms a protective layer on epithelial surfaces. Traps foreign particles and bacteria, when swallowed they are destroyed in stomach acid. In the digestive tract it lubricates and protects the stomack lining from the acid

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7
Q

Mucin structure

A

Mucin forms a part of mucus. The proteins backbone in mucin is highly O-glycosylated, it is also hygroscopic meaning it attracts and retains H2O. There is a D-domain either side of the protein backbone this allows the mucin to form disulphide bonds with other mucin molecules. The disulphide bonds allow for polymerisation which allows the formation of a hydrated gel lattice, as the glycosylation allows it to hold a lot of water.

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8
Q

Basic empirical formula of carbohydrates

A

(CH2O)n

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9
Q

Groups sugars can be defined by

A

Aldehydes-aldoses

Ketones-ketoses

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10
Q

Oligosaccharides

A

Carbohydrates are between 2 or 10 simple sugars

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11
Q

Disaccharides

A

Two monosaccharides joined by a glycosidic bond.

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12
Q

Glycosidic bond

A

Formed in a condensation reaction. Bond is named after the carbons which join up i.e. a 1-6 glyocsidic bond. Alpha and beta glycosidic bond, in beta the sugar molecule is switched upside down.

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13
Q

Starch

A

Type of polysaccharide. It is made of amylose (alpha 1,4 glycosidic bonds) and amylopectin (alpha 1,6 glycosidic bonds), which generates branching. It is very dense, and the branching means that it is easily broken down.

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14
Q

Cellulose

A

Beta 1,4 linked D glucose, very rigid forms structural component in plants. Insoluble and hard to digest.

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15
Q

Glycogen

A

Stores most glucose in humans. Mainly alpha 1,4 glycosidic bonds with some alpha 1,6 glycosidic bonds which allow for branching so it can be rapidly broken down

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16
Q

moles equation

A

moles= mass/mr

17
Q

molarity

A

The number of moles of a substance dissolved in a litre dm^3 of solution, measure of concentration.

18
Q

Molarity equation

A

Molarity= mol/ volume (litres)

19
Q

What is a millilitre equal to

A

1cm^3

20
Q

What is a litre equal to

A

1dm^3 and a 1000 cubic cm

21
Q

How changing the length of a side effects volume

A

In a cube if you are changing each side by a factor of ten you are changing the volume by a factor of a thousand

22
Q

Dividing square routes

A

10^x / 10^y = 10^(x/y)

23
Q

Squaring square roots

A

You multiply them together i.e. 5x3=15

24
Q

Concentration

A

Amount divided by volume i.e. g/l can also be expressed as % weight per volume or %weight by weight. You dissolve 10 grams of salt in 100 grams of water, what’s the percentage of the solution that is salt. Can also be expressed as %volume per volume, same as with weight but for volume.

25
Q

Dilution factor

A

Ratio of the two volumes, final volume divided by initial volume

26
Q

Osmosis

A

The passive movement of a solvent from an a region of low solute concentration to an area of high solute concentration across a semi-permeable membrane.

27
Q

Osmotic pressure

A

The pressure exerted by the flow of water across a membrane as determined by solute concentration

28
Q

Hypo-osmolar

A

An area of low solute concentration which the water moves from in osmosis

29
Q

Hyper-osmolar

A

An area of high solute concentration which the water moves to in osmosis

30
Q

Iso-osmolar

A

When the solute concentration is the same in both solutions and there is no net movement of solvent

31
Q

Hypotonic solution

A

The osmolarity is less than the cells, water moves into the cells and they expand

32
Q

Hypertonic solution

A

The solution has an osmolarity greater than the cell. Water moves out of the cell and the cell shrinks

33
Q

Isotonic solution

A

The solution has an osmolarity that equals the intracellular, there is no net change in cell size

34
Q

Mole

A

The amount of a substance compared to the number of atoms in 12grams of carbon 12

35
Q

Avogadro’s constant

A

6.02 x10^23

36
Q

Osmolarity

A

The concentration of a solution expressed as moles per litre, includes dissociated ions, so when you add 1mol of NaCl to water it will be 2 osmol

37
Q

Osmolarity

A

The concentration of a solution expressed as mMol per kg. The mass refers to the mass of the solvent and solute. Independent of temperature and pressure

38
Q

Adding or subtracting in scientific notation

A

You convert them to the same power then do it normally