Carbohydrates Flashcards
Carbs
Most abundant organic molecule in nature
Function of Carbs
Energy, Cell membrane components for intercellular communication, and bacterial cell walls
6-C Structures prefer…
to be in an aromatic shape C6H1206
Carbs most common configuration in body…
D configuration
Racemases
enzymes that conver simple sugars between the L and D forms
Monosaccharides
Glyceraldehyde –> Arabinose –>Glucose & Mannose
Glyceraldehyde –> Lyxose –> Galactose
Dihydroxyacetone –> Ribulose –> Fructose
Isomers
Compounds with the same chemical formula
EX: Glucose, Fructose, Galactose
Epimers
Monosaccharide differ around a specific C.
EX: Galactose and glucose around C4
Mannose and Glucose around C2
Enantiomers
Non-super imposable mirror images. They are chiral.
Anomers
Cyclization creates an anomeric C. This creates an alpha and beta configuration. They can spontaneously switch forms which is called mutarotation. They help maintain the equilibrium in the body.
EX: alpha-D-glucopyranose: synthesizes glycogen
beta-D-glucopyranose: synthesizes cellulose
Glycosidic Bonds
Link monosaccharides. C1 Galactose, C4 Glucose
a config = a bond, B config = b bond
Glycosyltransferase
enzyme that forms Glycosidic Bonds
Lactose bond type
galactosyl- B (1-4) glucose
Asparagine & Sugar bond type
N-glycosidic bond (due to NH)
Serine & Sugar bond type
O-glycosidic bond (due to OH)