Carbohydrates Flashcards
Carbohydrates
Most common organic molecules, contain C, H, and O in 1:2:1 ratio
Functions
Source of energy, building material, cell surface markers (for id and communication)
Monosaccharides
Simple sugars consisting of one sugar unit –> straight C chains or rings with OH groups, distinguished by # of C and type of carbonyl group (ex, glucose, galactose, fructose)
- Polar due to high proportion of hydroxyl and carbonyl groups (dissolves easily)
Monosaccharides: Structural Isomers
Molecules that contain same same molecular formula but different spatial arrangements, resulting in different properties –> ex. glucose vs galactose
Monosaccharides: Stereoisomers
Molecules with same structures, but one group is rotated differently, resulting in different molecule connections (ex. beta glycosidic linkages where beta glucose must alternate orientation)
Disaccharides (Ogliosaccharides)
Two simple sugars bonded together
–> 1-4 glycosidic linkages (condensation between two hydroxyl groups)
Common Disaccharides
Maltose = a-glucose + a- glucose
Lactose = a-glucose + a-galactose
Sucrose = a-glucose + a-fructose
Polysaccharides
Complex carbs - long chains of monosaccharides (have low solubility due to length)
Storage Polysaccharides
Starch and Glycogen - made up of a-glucose molecules
Starch
Main storage molecule in plants
(ex. potato starch: combo of amylose in straight chains & branched amylopectin –> animals use enzymes like amylase to breakdown into individual molecules)
Glycogen
Storage molecule in animals used to store excess glucose –> like amylopectin but more branched
- Small amounts stored in liver and muscle (used for energy during bouts of physical activity)
Structural Polysaccharides
Cellulose and Chitin - made up of b-glucose molecules
Cellulose
Primary structural polysaccharide in plants (component of cell walls)
- Beta 1-4 glycosidic linkages (zig zag pattern) resistant to starch breaking enzymes
- But causes roughage: passes through undigested and scrapes large intestine causing mucus production which lubricates feces
Chitin
Found in hard exoskeleton of insects & crustaceans, and cell walls of fungi
–> composed of modified cellulose material (nitrogen in group at 2’ carbon of b-glucose)