Calorimetry - Introduction Flashcards

1
Q

The two types of energy changes in chemical reactions can be classified by:

A
  1. Exothermic Reactions - Give off heat energy
  2. Endothermic Reactions - Absorb heat energy from their surroundings
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2
Q

What is Enthalpy?

Heat Content

A

The chemical energy stored in a substance

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3
Q

Ethalpy is often also reffered to as…

A

Enthalpy = Heat Content = H = Chemical Energy.

Energy can transform between chemical and heat energy. H measures that.

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4
Q

Define Heat of Reaction

A

Symbol ΔH is Heat of reaction.
It is the change during chemical reaction.

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5
Q

Give equation for ΔH

A

ΔH = H (products) - H (reactants)

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6
Q

Describe ΔH for exothermic reactions

A

-ΔH - losses heat

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7
Q

Describe ΔH for endothermic reactions

A

+ ΔH - gains heat

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8
Q

What is a thermochemical equation

A

A balanced chemical equation that includes its heat of reaction (ΔH)

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9
Q

What are the units used for ΔH?

A

J/mol or kJ/mol

Cannot write superscrip on here - ‘mol’ is usually denoted with power of negative 1

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10
Q

Describe relationship between mole ration of equation and ΔH

A

Directly proportional - Doubling reactants and products in equation doubles ΔH and vice versa

Note: ΔH is also different for states, eg: changing water form liquid to gas has different ΔH than from solid to liquid

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11
Q

Describe how Thermochemical equations can be manipulated?

A

They can be added or subtracted to produce new thermochemical equations.
Eg: Thermochemical equations for fusion (melting) + vaporisation (evaporation) = thermochemical equation for sublimation (solid to gas)

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