Calorimetry - Introduction Flashcards
The two types of energy changes in chemical reactions can be classified by:
- Exothermic Reactions - Give off heat energy
- Endothermic Reactions - Absorb heat energy from their surroundings
What is Enthalpy?
Heat Content
The chemical energy stored in a substance
Ethalpy is often also reffered to as…
Enthalpy = Heat Content = H = Chemical Energy.
Energy can transform between chemical and heat energy. H measures that.
Define Heat of Reaction
Symbol ΔH is Heat of reaction.
It is the change during chemical reaction.
Give equation for ΔH
ΔH = H (products) - H (reactants)
Describe ΔH for exothermic reactions
-ΔH - losses heat
Describe ΔH for endothermic reactions
+ ΔH - gains heat
What is a thermochemical equation
A balanced chemical equation that includes its heat of reaction (ΔH)
What are the units used for ΔH?
J/mol or kJ/mol
Cannot write superscrip on here - ‘mol’ is usually denoted with power of negative 1
Describe relationship between mole ration of equation and ΔH
Directly proportional - Doubling reactants and products in equation doubles ΔH and vice versa
Note: ΔH is also different for states, eg: changing water form liquid to gas has different ΔH than from solid to liquid
Describe how Thermochemical equations can be manipulated?
They can be added or subtracted to produce new thermochemical equations.
Eg: Thermochemical equations for fusion (melting) + vaporisation (evaporation) = thermochemical equation for sublimation (solid to gas)