C7 Organic Chemistry Flashcards

1
Q

what is a hydrocarbon?

A

any compound that is formed from carbon and hydrogen atoms only.

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2
Q

what is the simplest type of hydrocarbon?

A

alkanes

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3
Q

is the general form of an alkane

A

CnH2n+2

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4
Q

alkanes are homologous series what does this mean?

A

a group of organic compounds that react in a similar way

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5
Q

alkanes are saturated compounds, this means

A

each carbon atom forms four single covalent bonds

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6
Q

what are the first four alkanes

A

methane
ethane
propane
butane

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7
Q

the shorter the carbon chain……..

A

the less viscous the hydrocarbon is
the more volatile the hydrocarbon is
the more flammable the hydrocarbon is

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8
Q

what are short chain hydrocarbons used for

A

bottles gasses, stored under pressure as liquids in bottles

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9
Q

when does complete combustion occur?

A

when there plenty of oxygen

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10
Q

what does complete combustion of hydrocarbon in oxygen release

A

lots of energy

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11
Q

what are the waste products of complete combustion of hydrocarbons in oxygen?

A

carbon dioxide and water vapour

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12
Q

what happens to carbon and hydrogen in combustion?

A

they are oxidised, they gain oxygen

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13
Q

why are hrdocarbons used as fuels

A

they release a lot of energy when combust completely

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14
Q

what is crude oil

A

a fossil fuel

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15
Q

how is crude oil formed?

A

1) remains of plants and animals - mainly plankton, that died millions of years ago and were buried in mud.
2) over millions of years with high temp and pressure the remains turn to crude oil which can be drilled up from the rocks where its found.

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16
Q

what are some examples of fossil fuels?

A

coal, oil and gas

17
Q

are fossil fuels non renewable?

A

YES they are finite resources and will one day run out

18
Q

what is fractional distillation used to separate?

A

hydrocarbon fractions

19
Q

what is crude oil a mixture of

A

lots of different hydrocarbons, most are alkanes

20
Q

how does fractional distillation work?

A

1) the oil is heated until most of it has turned to gas. the gasses enter a factional distillation column (and the liquid is drained off)
2) in the column there is a temperature gradient (hot at the bottom and cooler as you go up)
3) the longer hydrocarbons have high boiling points. they condense back into liquids and drain out of the column early on, when they re near the bottom. the short hydrocarbons have lower boiling points. they condense and drain out much later on, near the top of the column where its cooler.
4) you end up with the crude oil mixture separated out into different fractions. each fraction contains a mixture of hydrocarbons that all contain a similar number of carbon atoms, so have similar boiling points.

21
Q

crude oil uses:

A

fuel for most modern transport - cars, trains, planes.
diesel
kerosene
heavy fuel oil
liquid petroleum gas

petrochemical inductry use hydrocarbons from crude oil as a feedstock to make new compounds for thiungs like:
polymers
solvents
lubricants
detergents

22
Q

uses of crude oil:

A

Crude oil is an important source of:

fuels such as petrol, diesel, kerosene, heavy fuel oil and liquefied petroleum gases
feedstock for the petrochemical industry
A feedstock is a raw material used to provide reactants for an industrial reaction. A petrochemical is a substance made from crude oil using chemical reactions. For example, ethene is produced from crude oil. It is used as feedstock to make poly(ethene), a polymer.

Other useful substances made from compounds found in crude oil include:

solvents
lubricants
detergents

23
Q

why does crude oil produce a large variety of products?

A

carbon atoms can bond together to form different groups called homologous series. these groups contain similar compounds with many properties in common.

24
Q

what are short chain hydrocarbons used for?

A

they are flammable so they are used for fuels, they are in high demand

25
Q

what are long chain carbons used for

A

they form thick gloppy liquids like tar they are not very useful

26
Q

what happens to long chain hydrocarbons

A

they are spilt up by cracking

27
Q

as well as alkanes what is also produced in cracking?

A

alkenes

28
Q

what are alkenes?

A

hydrocarbons used a a starting material when making lots of other compounds and can be used to make polymers

29
Q

how do you test for alkenes?

A

1) when orange bromine water is added to an alkane, no reaction will happen and it will stay bright orange

2) if bromine water is added to an alkene a reaction occurs because alkenes are more reactive than alkanes. this results in a colourless compound being produced and the bromine water being decolorised.

30
Q

what are the products of cracking used for?

A

fuels eg petrol for cars and paraffin for jet fuel

31
Q

what type of reaction is cracking?

A

a thermal decomposition reaction - breaking molecules down by heating them

32
Q

how to do cracking?

A

1) heat long chain hydrocarbons to vaporise them
2) the vapour can be passed over a hot powdered aluminium oxide catalyst
3) the long chain molecules split apart on the surface of the specks of catalyst - this is catalytic cracking

33
Q

what is steam cracking:

A

vaporising the long chain hydrocarbon
mix it with steam
heat in very high temp