C5 Hydrothermal Processing Flashcards

1
Q

principle hyrothermal processing

A

ultilise subcritical and supercritical water medium at elevated temp(200-800) and pressure(5-30MPa)

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2
Q

advantage hyrothermal

4 advantages

A
  1. acceptance of wet biomas & mixed feedstock
  2. selectivity of products
  3. product seperation
  4. energy efficiency
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3
Q

4 categories

A
  1. torwash (extract water,remove salt)
  2. hydrothermal carbonisation (produce hydrochar)
  3. hydrothermal liquefaction (produce bio-oil)
  4. hydrothermal gasification (produce gas)
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4
Q

factors affecting hydrothermal liquefaction

A
  1. biomass type&composition
  2. biomass particle size&heating rate
  3. residence time associate with type of reactor
  4. temperature
  5. pressure
  6. catalyst
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5
Q

type of reactor

A
  1. batch reactor
  2. continous batch reactor
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6
Q

type catalyst

A
  1. alkaline catalyst - enhance bio-oil,supress char formation
  2. acid catalyst- increase formation water soluble compound such as carboxylic acid
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7
Q

engineering obstacle&challenges

A
  1. reactor design
  2. biomass loading in the feed (↓output but ↑ cost)
  3. salt precipitate (cause clogging. solution: introduce strring within reactor- prevent salt accumulate on reactor wall)
  4. catalyst problems
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8
Q

catalyst problems

type catalyst

A
  1. heterogenous
    * advantage: easy seperation (liq & solid)
    * disadvantage: deactivation process
  2. homogenous
    * advantage: free deactivation
    * disadvantage: seperate& recovery catalyst
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