C2 Combustion of Biomass Flashcards
combustion process
- biomass undergoes devotilization
- it produce votile flame that contain votile gas with help of O2
- then combustion process occur produce charcoal and CO2 gas released
4 stage of biomass combustion
- drying
- devotilization
- combustion of votiles
- combustion of char
votile gas
- CH4
- C2H6
- CO
- CO2
- H2O
- H2
drying process
- remove/evaporate moisture content
- important because if moisture >65% heat by combustionn not effision
- take away large amount energy and keep biomass at low temp= called “cooling phenomenon”
cooling process
disable the ignition of biomass before sufficient extraction of water
devotilization process
- dry biomass turn into tars + votile gases + solid char
combustion of votiles process
tars + votile gases + O2(Iin air) ignited&combusted into heat + light + by products (CO,CO2,H2O,soot)
* exothermic reaction
combustion of char
char + O2(in air) turn into CO + CO2 + other pollutants
* it occur simultaneously with combustion of votiles
* more exothemic, has lower Ea, much slower reaction speed
factors influencing combustion performance
- biomass properties (physical&chemical)
- biomass feeding stock
- combustion air distribution & amount
- operational condition (temp, P, retention time)
- furnace type &design
biomass properties
physical structure
- particle size ↑, delay ignition of votiles,tar quantity ↑
- density
- surface area ↑, efficency ↑
biomass properties
chemical property
- moisture & ash content ↑, flame temp ↓
- element composition (K, Na, Cl)
co-firing biomass with coal process
coal + biomass → reduce consumption coal to generate electricity
co-firing biomass with coal benefit
- not require modify existing facility
- lower SO2 emssion
- contribute to lowering CO2 emission - biomass = CO2 neutral free
- ↑ ultize efficency biomass
3 basic co-firing technolgy
- direct co-firing
- parellel co-firing
- indirect co-firing
direct co-firing
pre-mix biomass + coal →(fed into) combustion with coal
parellel co-firing
seperatly combust biomass & coal, steam produce → converge
indirect co-firing
- combust biomass → gas
- gas combust with coal
pollutant type from biomass combustion
- gases
- metals
- particles
pollutant type
gases
- incomplete combustion
* CO, NH3, VOCs - complete combustion
* CO2,NO,NO2,SO2
pollutant type
metals
hazadous metal
Cd & Hg
pollutant type
particles
- PM=particle matter emission
- type PM
1. PM10 = inhalable with particle size <10μm
2. PM2.5 = inhalable with particle size <2.5μm
3 factors affecting PM
measure for pollutant reduction
* biomass properties
-Ash related element (K,Cl,Na,Mg&P)
-high water content - incomplete combustion-emit CO &pollutant
* combustion parameter
-method to reduce pollutant = good mixing biomass with primary air & mixing the produce combustible gases with excess air
* reactor type